New access to 1,3-diketones from aldehydes

doi:10.1016/j.tet.2004.07.087

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New access to 1,3-diketones from aldehydes

Publication Type

Publication

Publication date

2004-11

Language

English

Full Text

http://archimer.ifremer.fr/doc/2004/publication-829.pdf (0.24 Mo)

Author(s)

Fargeas Valérie, Baalouch Myriam, Metay Estelle, Baffreau Jerôme, Menard Dominique, Gosselin Pascal, Berge Jean-Pascal, Barthomeuf Chantal, Lebreton Jacques

Affiliation(s):

CNRS, Fac Sci & Tech, UMR 6513, Organ Synth Lab, F-44322 Nantes 3, France.
Univ Maine, Fac Sci, CNRS, UMR 6511,Lab Synth Organ, F-72085 Le Mans, France.
IFREMER, Dept Valorisat Prod Mer, F-44311 Nantes 3, France.
Univ Auvergne, Fac Pharm, Lab Pharmacognosie & Biotechnol, UMR,U 484,INSERM, F-63001 Clermont Ferrand, France.

Source:

Tetrahedron (0040-4020) (Elsevier), 2004-11 , Vol. 60 , N. 45 , P. 10359-10364

DOI:

10.1016/j.tet.2004.07.087

Subject(s)

Biology

Keyword(s)

1,3 diketones, Alkylation, Sulfones, Aldehydes

Abstract

A simple and efficient methodology to introduce an 1,3-diketone motif from various aldehyde precursors in three steps with good overall yields is described using beta-ketosulphone 7 as masked equivalent of acetone.

How to cite this document:

Fargeas Valérie, Baalouch Myriam, Metay Estelle, Baffreau Jerôme, Menard Dominique, Gosselin Pascal, Berge Jean-Pascal, Barthomeuf Chantal, Lebreton Jacques (2004). New access to 1,3-diketones from aldehydes. Tetrahedron, 60(45), 10359-10364. Publisher's official version : http://dx.doi.org/10.1016/j.tet.2004.07.087 , Open Access version : http://archimer.ifremer.fr/doc/00000/829/