FN Archimer Export Format PT J TI Authigenic carbonates from methane seeps of the Congo deep-sea fan BT AF PIERRE, Catherine FOUQUET, Yves AS 1:1;2:2; FF 1:;2:PDG-DOP-DCB-GM-LGM; C1 UPMC, UMR 7159, LOCEAN, F-75252 Paris 05, France. IFREMER, Geosci Marines, Technopole Iroise, F-29280 Plouzane, France. C2 UNIV PARIS 06, FRANCE IFREMER, FRANCE SI BREST SE PDG-DOP-DCB-GM-LGM IN WOS Ifremer jusqu'en 2018 copubli-france copubli-univ-france IF 0.811 TC 58 TU Centre national de la recherche scientifique Institut de recherche pour le développement Muséum national d'histoire naturelle Université Pierre et Marie Curie UR https://archimer.ifremer.fr/doc/2007/publication-2608.pdf LA English DT Article CR BIOZAIRE 1 BIOZAIRE 3 ZAIANGO-BIOL2 ZAIANGO1 ZAIANGO2 BO Unknown Anchored Buoy Thalassa L'Atalante DE ;oxygen isotopes;carbon isotopes;Congo deep sea fan;gas hydrate;methane seep;authigenic carbonate AB Submersible investigations with the ROV Victor 6000 of some pockmark structures on the seafloor of the Congo deep-sea fan have shown that they are active venting sites of methane-rich fluids, associated with abundant fauna and carbonate crusts. Moreover, methane hydrates have been observed both outcropping and deep in the sediments in the centre of the "Regab" giant pockmark. Authigenic carbonates, mostly calcite sometimes mixed with aragonite, are cementing the sedimentary matrix components and fauna; diatoms are abundant but only as moulds, indicating that biogenic silica dissolution occurred in situ synchronous with carbonate precipitation. The occurrence of diagenetic barite and pyrite in some carbonate crusts demonstrates that they can be formed either within the sulphate/methane transition zone or deeper in sulphate-depleted sediments. The oxygen isotopic compositions of the diagenetic carbonates (3.17-6.01 parts per thousand V-PDB) indicate that precipitation occurred with bottom seawater mixed with a variable contribution of water from gas hydrate decomposition. The very low carbon isotopic compositions of the diagenetic carbonates (-57.1 to -27.75 parts per thousand V-PDB) demonstrate that carbon derives mostly from the microbial oxidation of methane. PY 2007 PD JUL SO Geo-Marine Letters SN 0276-0460 PU Springer VL 27 IS 2-4 UT 000247204200017 BP 249 EP 257 DI 10.1007/s00367-007-0081-3 ID 2608 ER EF