FN Archimer Export Format PT J TI Sr/Ca and Mg/Ca ratios in Niger Delta sediments: Implications for authigenic carbonate genesis in cold seep environments BT AF BAYON, Germain PIERRE, C ETOUBLEAU, Joel VOISSET, Michel CAUQUIL, E MARSSET, Tania SULTAN, Nabil LE DREZEN, Eliane FOUQUET, Yves AS 1:1;2:2;3:1;4:1;5:3;6:1;7:1;8:1;9:1; FF 1:PDG-DOP-DCB-GM-LGM;2:;3:PDG-DOP-DCB-GM-LGM;4:PDG-DOP-DCB-GM-CTD;5:;6:PDG-DOP-DCB-GM-LES;7:PDG-DOP-DCB-GM-LES;8:PDG-DOP-DCB-GM-CTD;9:PDG-DOP-DCB-GM-LGM; C1 IFREMER, Dept Geosci Marines, Brest, France. Univ Paris 06, LOCEAN, Paris, France. TOTAL, Paris, France. C2 IFREMER, FRANCE UNIV PARIS 06, FRANCE TOTAL, FRANCE SI BREST SE PDG-DOP-DCB-GM-LGM PDG-DOP-DCB-GM-CTD PDG-DOP-DCB-GM-LES IN WOS Ifremer jusqu'en 2018 copubli-france copubli-univ-france IF 1.975 TC 112 UR https://archimer.ifremer.fr/doc/2007/publication-2696.pdf LA English DT Article DE ;Niger Delta;Gas hydrates;Cold seeps;Mg/Ca;Sr/Ca;Authigenic carbonates AB We report on a reconnaissance analysis of the geochemical composition of authigenic carbonates and sediment samples collected from various seepage sites on the Niger deep-sea fan. Our aim has been to investigate whether evidence for the presence of authigenic carbonates and gas hydrates within sediments is discernible from solid-phase sediment geochemistry. We show that sedimentary Sr/Ca and Mg/Ca ratios can be used to infer the presence of authigenic aragonite (Sr-rich) and Mg-rich carbonate phases (high-Mg calcite, dolomite) in cold seep settings. Using Sr/Ca and Mg/Ca ratios, the proportion (wt.%) of authigenic carbonates in Niger Fan sediments can be calculated from a mixing model between sediment fractions of terrigenous material, biogenic calcite, aragonite and high-Mg calcite. This approach was applied to high-resolution geochemical profiles along sediment cores recovered from various cold seep settings (mud volcano, diapirs, pockmarks, gas-hydrate bearing sediments). Our data reveal that authigenic carbonates occur as discrete phases in sediments from gas-hydrate-bearing areas, suggesting that such carbonate-rich sediment layers may represent paleo-indicators for ancient methane seepage in marine sediments, possibly associated to gas-hydrate reservoirs. (C) 2007 Elsevier B.V. All rights reserved. PY 2007 PD JUL SO Marine Geology SN 0025-3227 PU Elsevier VL 241 IS 1-4 UT 000247737200007 BP 93 EP 109 DI 10.1016/j.margeo.2007.03.007 ID 2696 ER EF