FN Archimer Export Format PT J TI Interactions between Volatile Reduced Sulfur Compounds and Metals in the Seine Estuary (France) BT AF COZIC, Amandine VIOLLIER, E CHIFFOLEAU, Jean-Francois KNOERY, Joel ROZUEL, Emmanuelle AS 1:1;2:2,3;3:4;4:4;5:4; FF 1:PDG-DOP-DCN-BE-LBCM;2:;3:PDG-DOP-DCN-BE-LBCM;4:PDG-DOP-DCN-BE;5:PDG-DOP-DCN-BE-LBCM; C1 Intechmer, CNAM, F-50103 Cherbourg, France. Univ Paris Diderot, Lab Geochim Eaux, F-75251 Paris 05, France. IPGP, F-75251 Paris 05, France. IFREMER, Dept DCN BE, F-44311 Nantes, France. C2 INTECHMER, FRANCE UNIV PARIS 07, FRANCE IPGP, FRANCE IFREMER, FRANCE SI NANTES SE PDG-DOP-DCN-BE-LBCM PDG-DOP-DCN-BE IN WOS Ifremer jusqu'en 2018 copubli-france copubli-univ-france IF 1.408 TC 8 UR https://archimer.ifremer.fr/doc/2008/publication-5019.pdf LA English DT Article DE ;Conditional stability constant;Metal;Volatile reduced sulfur compounds;Seine estuary AB Concentrations of volatile hydrogen sulfide (H2S), carbonyl sulfide (OCS), methane thiol (MeSH), dimethyl sulfide (DMS), and dimethyl disulfide (DMDS) in the Seine estuary (France) were investigated in spring 2005 using samples collected from the first meter beneath the surface. Levels of dissolved metals (Ag, Cd, Cu, Zn, Ni, Co, Pb), suspended particulate matter, and particular organic carbon were also assessed. Maximum concentrations were 0.80 nM for H2S, 0.64 nM for OCS, 3.06 nM for MeSH, 11.06 nM for DMS, and 1.18 nM for DMDS, and different features were observed for the five volatile reduced sulfur compounds (VRSCs). Experiments were conducted to determine silver-VRSC conditional stability constants. Major interactions were observed between H2S and Ag, which may partially account for the absence of volatile H2S at the lowest salinities. OCS, MeSH, and DMS did not interact with Ag, as revealed by their insignificant K' values. Variations in concentrations along the salinity gradient may be explained by the influence of phytoplanktonic compounds. PY 2008 PD DEC SO Estuaries and coasts : Journal of the Estuarine Research Federation SN 1559-2723 PU Estuaries Research Federation VL 31 IS 6 UT 000260686700004 BP 1063 EP 1071 DI 10.1007/s12237-008-9099-7 ID 5019 ER EF