FN Archimer Export Format PT J TI Seawater ageing of flax/poly(lactic acid) biocomposites BT AF LE DUIGOU, A. DAVIES, Peter BALEY, C. AS 1:2;2:1;3:2; FF 1:;2:PDG-DOP-DCB-ERT-MS;3:; C1 IFREMER, Mat & Struct Grp, Ctr Brest, F-29280 Plouzane, France. Equipe Polymeres & Composites, LIMATB Lab Ingn Mat Bretagne, F-56321 Lorient, France. C2 IFREMER, FRANCE UBS, FRANCE SI BREST SE PDG-DOP-DCB-ERT-MS IN WOS Ifremer jusqu'en 2018 copubli-france copubli-univ-france IF 2.154 TC 152 UR https://archimer.ifremer.fr/doc/2009/publication-6639.pdf LA English DT Article DE ;Mechanical properties;Hygrothermal ageing;Biopolymer;Natural fibre;Composites AB Natural fibre reinforced biopolymer composites, or biocomposites, are an alternative to the glass fibre reinforced thermoset composites widely used today in marine applications. Biocomposites offer good mechanical properties and total biodegradability, but if they are to be adopted for marine structures their durability in a seawater environment must be demonstrated. In the present study unreinforced PLLA (Poly(L-Lactic acid)), injected and film stacked flax composites with the same PLLA matrix have been examined. All the samples were aged in natural seawater at different temperatures in order to accelerate hygrothermal ageing. Changes to physico-chemical and mechanical behaviour have been followed by weight measurements, thermal and gel permeation chromatography (GPC) analyses, and tensile testing, completed by acoustic emission recording and scanning electron microscopy (SEM) examination. The matrix tensile stiffness is hardly affected by seawater at temperatures to 40 degrees C but the composite loses stiffness and strength. Fibre/matrix interface weakening is the main damage mechanism induced by wet ageing, but both matrix and fibre cracks also appear at longer periods. (C) 2009 Elsevier Ltd. All rights reserved. PY 2009 PD JUN SO Polymer Degradation and Stability SN 0141-3910 PU Elsevier VL 94 IS 7 UT 000267815700016 BP 1151 EP 1162 DI 10.1016/j.polymdegradstab.2009.03.025 ID 6639 ER EF