FN Archimer Export Format
PT J
TI Gas chromatographic behavior of fatty acid derivatives for mass spectrometry on low-polarity capillary columns
BT 
AF DUBOIS, Nolwenn
   BARNATHAN, Gilles
   GOUYGOU, Jean-Paul
   BERGE, Jean-Pascal
AS 1:;2:2;3:;4:1;
FF 1:PDG-DOP-DCN-BRM-PBA;2:;3:PDG-DOP-DCN-BRM-STBM;4:PDG-DOP-DCN-BRM-STBM;
C1 IFREMER, Ctr Nantes, Dept Sci & Tech Alimentaires Marines, Lab Sci & Tech Alimentaires Marines, F-44311 Nantes 3, France.
   Univ Nantes, Nantes Atlantique Univ, Fac Pharm, Grp Mer Mol Sante MMS,EA 2160, F-44035 Nantes, France.
C2 IFREMER, FRANCE
   UNIV NANTES, FRANCE
SI NANTES
SE PDG-DOP-DCN-BRM-PBA
   PDG-DOP-DCN-BRM-STBM
IN WOS Ifremer jusqu'en 2018
   copubli-france
   copubli-univ-france
IF 1.831
TC 11
UR https://archimer.ifremer.fr/doc/2009/publication-6846.pdf
LA English
DT Article
DE ;Picolinyl esters;N Acyl pyrrolidides;Methyl esters;GC MS;Fatty acid derivatives;4,4 Dimethyloxazoline
AB The gas chromatographic properties of four derivatives of fatty acids (FA), namely fatty acid methyl esters, picolinyl esters, N-acyl pyrrolidides and 4,4-dimethyloxazoline derivatives, which contain various structural features (double bonds, branching, hydroxyl group) in their acyl chains have been compared on a low-polarity capillary column with a mass spectrometer as detector. Temperature programming rates yielding the highest resolution were optimized for each derivative by means of computer-assisted column temperature optimization software. Indeed, the Drylab software represents a valuable assistance for estimating the optimum analysis conditions. Time and efforts required for such method development can greatly be reduced. Different parameters (derivatization procedure, total run time, resolution and response factor) are discussed. N-Acyl pyrrolidides and picolinyl esters appear quite powerful for structure elucidation of polyunsaturated FA by GC-MS, and both these types of FA derivatives can be very well separated on a low-polarity phase.
PY 2009
PD JUN
SO European Journal of Lipid Science and Technology
SN 1438-7697
PU Wiley / Blackwell
VL 111
IS 7
UT 000268612300008
BP 688
EP 697
DI 10.1002/ejlt.200800148
ID 6846
ER

EF