FN Archimer Export Format PT J TI A benthic Si mass balance on the Congo margin: Origin of the 4000 m DSi anomaly and implications for the transfer of Si from land to ocean BT AF RAGUENEAU, O. REGAUDIE-DE-GIOUX, A. MORICEAU, B. GALLINARI, M. VANGRIESHEIM, Annick BAURAND, F. KHRIPOUNOFF, Alexis AS 1:1;2:1;3:1;4:1;5:2;6:2;7:2; FF 1:;2:;3:;4:;5:PDG-DOP-DCB-EEP-LEP;6:;7:PDG-DOP-DCB-EEP-LEP; C1 Inst Univ Europeen Mer, CNRS, UMR 6539, F-29280 Plouzane, France. IFREMER, Ctr Brest, Dep DEEP LEP, F-29280 Plouzane, France. C2 UBO, FRANCE IFREMER, FRANCE SI BREST SE PDG-DOP-DCB-EEP-LEP IN WOS Ifremer jusqu'en 2018 copubli-france copubli-univ-france IF 1.965 TC 24 TU Centre national de la recherche scientifique Institut de recherche pour le développement Institut français de recherche pour l'exploitation de la mer Université de Bretagne Occidentale UR https://archimer.ifremer.fr/doc/2009/publication-7410.pdf LA English DT Article CR BIOZAIRE 3 EQUALANT 2000 BO Anchored Buoy Thalassa DE ;Congo;Continental margin;Preservation;Dissolution;Biogenic silica AB To elucidate the origin of the silicic acid (DSi) anomaly observed along the 4000 isobath on the Congo margin, we have established a benthic Si mass balance and performed direct measurements of biogenic silica (bSiO(2)) dissolution in the deep waters and in the sediments. Results strongly suggest that the anomaly originates from the sediments; the intensity of DSi recycling is consistent with the degradation of organic matter, as observed from Si:O-2 ratios in the benthic fluxes compared to that ratio observed in the anomalies. Strong imbalances, observed in both the Si and C mass balances, suggest that the biogenic matter that degrades and dissolves in these sediments near 4000 m does not come from pelagic sedimentation. It is probably not coming also from the deep channel, because observations were similar in the deep channel vicinity (site D) and further south, far from its influence (site C). The composition of the sediments, with an Si:C ratio close to that observed on continental shelves, suggests that this matter is coming from downslope transport. A first estimate of the magnitude of this flux at global scale, close to 12 T mol Si yr(-1), suggests that it may be an important path for transferring Si from land to ocean. PY 2009 PD NOV SO Deep Sea Research Part II: Topical Studies in Oceanography SN 0967-0645 PU Elsevier VL 56 IS 23 UT 000272366000005 BP 2197 EP 2207 DI 10.1016/j.dsr2.2009.04.003 ID 7410 ER EF