FN Archimer Export Format PT J TI First Steps of in Situ Surface-Enhanced Raman Scattering During Shipboard Experiments BT AF PERON, Olivier RINNERT, Emmanuel COLAS, Florent LEHAITRE, Michel COMPERE, Chantal AS 1:2;2:1;3:1;4:1;5:1; FF 1:;2:PDG-DOP-DCB-RDT-IC;3:PDG-DOP-DCB-RDT-IC;4:PDG-DOP-DCB-ERT-IC;5:PDG-DOP-DCB-RDT-IC; C1 IFREMER, Serv Interfaces & Capteurs, F-29280 Plouzane, France. C2 IFREMER, FRANCE CEDRE, FRANCE SI CEDRE BREST SE CEDRE PDG-DOP-DCB-RDT-IC PDG-DOP-DCB-ERT-IC IN WOS Ifremer jusqu'en 2018 copubli-france IF 1.729 TC 11 UR https://archimer.ifremer.fr/doc/00016/12691/9718.pdf LA English DT Article DE ;Surface-enhanced Raman scattering;SERS;Chemosensors;Flow cells;Shipboard experiments;In situ measurements;Freundlich isotherm AB It is shown that the surface-enhanced Raman scattering (SERS) technique can be applied to detect organic molecules during in situ experiments. To this purpose, we used trans-1,2-bis(4-pyridyl)ethylene (BPE) as a target molecule. Adsorbed on the SERS chemosensor surface and excited under laser, the vibration modes of the molecules can be identified. SERS chemosensors are based on quartz substrates functionalized by silanization and partially coated with gold nanoparticles. SERS measurements during shipboard experiments were made with a home-made in situ Raman spectrometer connected to a marinized micro-fluidic system. The device was designed to host chemosensors in order to ensure measurements with a flow cell. A theoretical limit of detection was estimated in the range of picomolar (pM) concentrations based on Freundlich isotherm calculations. PY 2010 PD OCT SO Applied Spectroscopy SN 0003-7028 PU Soc Applied Spectroscopy VL 64 IS 10 UT 000282855500003 BP 1086 EP 1093 DI 10.1366/000370210792973505 ID 12691 ER EF