FN Archimer Export Format PT J TI Glacial influence on the geochemistry of riverine iron fluxes to the Gulf of Alaska and effects of deglaciation BT AF SCHROTH, Andrew W. CRUSIUS, John CHEVER, Fanny BOSTICK, Benjamin C. ROUXEL, Olivier AS 1:1;2:2,3;3:4;4:5;5:4,6,7; FF 1:;2:;3:;4:;5:PDG-REM-GM-LGM; C1 Woods Hole Coastal and Marine Science Center, U.S. Geological Survey, Woods Hole, Massachusetts, USA Woods Hole Coastal and Marine Science Center, U.S. Geological Survey, Woods Hole, Massachusetts, USA University of Washington, Coastal and Marine Geology Program, U.S. Geological Survey, School of Oceanography, Seattle, Washington, USA European Institute for Marine Studies, University of Brest, Technopôle Brest-Iroise, Plouzané, France Lamont-Doherty Earth Observatory, Palisades, New York, USA Department of Marine Chemistry and Geochemistry, Woods Hole Oceanographic Institution, Woods Hole, Massachusetts, USA IFREMER, Centre de Brest, Plouzané, France C2 WOODS HOLE, USA WOODS HOLE, USA UNIVERSITY OF WASHINGTON, USA UBO, FRANCE LDEO, USA WOODS HOLE, USA IFREMER, FRANCE SI BREST SE PDG-REM-GM-LGM IN WOS Ifremer jusqu'en 2018 copubli-france copubli-univ-france copubli-int-hors-europe IF 3.792 TC 38 UR https://archimer.ifremer.fr/doc/00044/15483/12872.pdf LA English DT Article AB Riverine iron (Fe) derived from glacial weathering is a critical micronutrient source to ecosystems of the Gulf of Alaska (GoA). Here we demonstrate that the source and chemical nature of riverine Fe input to the GoA could change dramatically due to the widespread watershed deglaciation that is underway. We examine Fe size partitioning, speciation, and isotopic composition in tributaries of the Copper River which exemplify a long-term GoA watershed evolution from one strongly influenced by glacial weathering to a boreal-forested watershed. Iron fluxes from glacierized tributaries bear high suspended sediment and colloidal Fe loads of mixed valence silicate species, with low concentrations of dissolved Fe and dissolved organic carbon (DOC). Iron isotopic composition is indicative of mechanical weathering as the Fe source. Conversely, Fe fluxes from boreal-forested systems have higher dissolved Fe concentrations corresponding to higher DOC concentrations. Iron colloids and suspended sediment consist of Fe (hydr)oxides and organic complexes. These watersheds have an iron isotopic composition indicative of an internal chemical processing source. We predict that as the GoA watershed evolves due to deglaciation, so will the source, flux, and chemical nature of riverine Fe loads, which could have significant ramifications for Alaskan marine and freshwater ecosystems. Citation: Schroth, A. W., J. Crusius, F. Chever, B. C. Bostick, and O. J. Rouxel (2011), Glacial influence on the geochemistry of riverine iron fluxes to the Gulf of Alaska and effects of deglaciation, Geophys. Res. Lett., 38, L16605, doi:10.1029/2011GL048367. PY 2011 PD AUG SO Geophysical Research Letters SN 0094-8276 PU Amer Geophysical Union VL 38 IS L16605 UT 000294368100002 DI 10.1029/2011GL048367 ID 15483 ER EF