FN Archimer Export Format PT J TI Iron isotope constraints on the Archean and Paleoproterozoic ocean redox state BT AF ROUXEL, Olivier BEKKER, A EDWARDS, KJ AS 1:;2:;3:; FF 1:;2:;3:; C1 Woods Hole Oceanog Inst, Marine Chem & Geochem Dept, Geomicrobiol Grp, Woods Hole, MA 02543 USA. Carnegie Inst Washington, Geophys Lab, Washington, DC 20015 USA. C2 Woods Hole Oceanog Inst, Marine Chem & Geochem Dept, Geomicrobiol Grp, Woods Hole, MA 02543 USA. Carnegie Inst Washington, Geophys Lab, Washington, DC 20015 USA. IF 30.927 TC 357 UR https://archimer.ifremer.fr/doc/00078/18965/16580.pdf LA English DT Article AB The response of the ocean redox state to the rise of atmospheric oxygen about 2.3 billion years ago (Ga) is a matter of controversy. Here we provide iron isotope evidence that the change in the ocean iron cycle occurred at the same time as the change in the atmospheric redox state. Variable and negative iron isotope values in pyrites older than about 2.3 Ga suggest that an iron-rich global ocean was strongly affected by the deposition of iron oxides. Between 2.3 and 1.8 Ga, positive iron isotope values of pyrite likely reflect an increase in the precipitation of iron sulfides relative to iron oxides in a redox stratified ocean. PY 2005 PD FEB SO Science SN 0036-8075 PU Amer Assoc Advancement Science VL 307 IS 5712 UT 000227197300042 BP 1088 EP 1091 DI 10.1126/science.1105692 ID 18965 ER EF