FN Archimer Export Format PT J TI Coupling moisture diffusion and internal mechanical states in polymers - A thermodynamical approach BT AF SAR, B. E. FREOUR, S. DAVIES, Peter JACQUEMIN, Frederic AS 1:1;2:1;3:2;4:1; FF 1:;2:;3:PDG-REM-RDT-MS;4:; C1 Univ Nantes, Ecole Cent Nantes, LUNAM Univ, Inst Rech Genie Civil & Mecan,UMR CNRS 6183, F-44602 St Nazaire, France. IFREMER, Serv Mat & Struct, Ctr Brest, F-29280 Plouzane, France. C2 UNIV NANTES, FRANCE IFREMER, FRANCE SI BREST SE PDG-REM-RDT-MS IN WOS Ifremer jusqu'en 2018 copubli-france copubli-univ-france IF 1.59 TC 34 UR https://archimer.ifremer.fr/doc/00088/19932/17755.pdf LA English DT Article DE ;Hygromechanical coupling;Moisture absorption;Thermodynamical approach AB A thermodynamical approach, based on the definition of the chemical potential of water, is used in order to establish a model coupling the diffusion of moisture to the mechanical behaviour of a polymer. The model takes into account the evolution, occurring during the diffusion process, of both the density of the polymer and its maximum moisture absorption capacity. The approach developed is applied to symmetric loading cases, in terms of relative humidity and external pressure. The model, established in the present work, provides the water content profiles through the thickness of the polymer throughout the transient phase of the diffusion process. The numerical results obtained show the significant effect of an external pressure on the kinetics of moisture diffusion in polymers. (C) 2012 Elsevier Masson SAS. All rights reserved. PY 2012 PD NOV SO European Journal Of Mechanics A-solids SN 0997-7538 PU Gauthier-villars/editions Elsevier VL 36 UT 000305670400005 BP 38 EP 43 DI 10.1016/j.euromechsol.2012.02.009 ID 19932 ER EF