FN Archimer Export Format PT J TI Spatio-temporal variability in benthic silica cycling in two macrotidal estuaries: Causes and consequences for local to global studies BT AF RAIMONET, Melanie RAGUENEAU, Olivier ANDRIEUX LOYER, Francoise PHILIPPON, Xavier KEROUEL, Roger LE GOFF, Manon MEMERY, Laurent AS 1:1;2:1;3:2;4:2;5:2;6:1;7:1; FF 1:;2:;3:PDG-ODE-DYNECO-PELAGOS;4:PDG-ODE-DYNECO-PELAGOS;5:PDG-ODE-DYNECO-PELAGOS;6:;7:; C1 Inst Univ Europeen Mer, UMR CNRS UBO IRD Ifremer 6539, Lab Sci Environm Marin LEMAR, Plouzane, France. IFREMER, DYNECO Pelagos, Plouzane, France. C2 UBO, FRANCE IFREMER, FRANCE SI BREST SE PDG-ODE-DYNECO-PELAGOS IN WOS Ifremer jusqu'en 2018 copubli-france copubli-univ-france IF 2.253 TC 16 UR https://archimer.ifremer.fr/doc/00124/23529/21365.pdf https://archimer.ifremer.fr/doc/00124/23529/22370.pdf LA English DT Article DE ;heterogeneity;season;silicate;sediment;land-sea interface;upscaling AB The high heterogeneity of silica cycling in coastal margins and the lack of silica data (compared to nitrogen and phosphorus) prevent the estimation of global silica retention in estuaries. In this study, the spatial and temporal variability of porewater silicic acid (Si(OH)4) profiles e that integrate benthic transport and reaction processes e was investigated at different spatial (metre, longitudinal and crosssection, intra-estuary) and temporal (tidal, seasonal) scales in two macrotidal estuaries, very close geographically but essentially differing in their shape. Studying the spatial and temporal variability of Si(OH)4 concentrations in porewaters provided evidence for the importance of transport processes, e.g. bio-irrigation, tidal pumping, resuspension and any combination of these processes, in affecting Si(OH)4 concentrations and fluxes and therefore temporary or permanent retention along the landeocean continuum. We confirm that aSiO2 (amorphous silicate) transported by rivers and estuaries clearly needs to be better characterized as it provides an important source of reactive aSiO2 to sediments. This study allows us to: (1) interrogate spatial and temporal scales, although both are most often in complete interaction; (2) design the most appropriate sampling schemes to be representative of any given system and to extrapolate at the scale of the whole estuary; (3) quantify uncertainty associated to the estimations of Si(OH)4 stocks and fluxes in this type of ecosystem, essential for budget calculations. We showed that two adjacent small macrotidal estuaries, may exhibit different behaviours regarding Si retention. Temporary retention has been observed in the meanders of the Aulne Estuary and not along the more linear Elorn Estuary, demonstrating the importance of the morphology and hydrodynamic components of the estuarine filter. Research is needed in other systems and climatic zones, but our study suggests that the typology should not only account for the different types of landeocean continuum (fjord, delta, mangrove.), but also incorporate the physical or biological attributes of the estuarine filter. PY 2013 PD MAR SO Estuarine Coastal And Shelf Science SN 0272-7714 PU Academic Press Ltd- Elsevier Science Ltd VL 119 UT 000316427900004 BP 31 EP 43 DI 10.1016/j.ecss.2012.12.008 ID 23529 ER EF