FN Archimer Export Format PT J TI Investigation on the geochemical dynamics of a hydrate-bearing pockmark in the Niger Delta BT AF RUFFINE, Livio CAPRAIS, Jean-Claude BAYON, Germain RIBOULOT, Vincent DONVAL, Jean-Pierre ETOUBLEAU, Joel BIROT, Dominique PIGNET, Patricia RONGEMAILLE, Emmanuelle CHAZALLON, Bertrand GRIMAUD, Sylvie ADAMY, Jerome CHARLOU, Jean-Luc VOISSET, Michel AS 1:1;2:2;3:1;4:1;5:1;6:1;7:1;8:2;9:1;10:3;11:4;12:4;13:1;14:1; FF 1:PDG-REM-GM-LGM;2:PDG-REM-EEP-LEP;3:PDG-REM-GM-LGM;4:PDG-REM-GM-LES;5:PDG-REM-GM-LGM;6:PDG-REM-GM-LGM;7:PDG-REM-GM-LGM;8:PDG-REM-EEP-LMEE;9:PDG-REM-EEP-LMEE;10:;11:;12:;13:PDG-REM-GM-LGM;14:PDG-REM-GM-CTDI; C1 IFREMER, Ctr Brest, Unite Rech Geosci Marines, F-29280 Plouzane, France. IFREMER, Ctr Brest, Unite Rech & Etud Environm Profonds, F-29280 Plouzane, France. Univ Lille 1, UMR CNRS 8523, CERLA FR CNRS 2416, Lab Phys Lasers Atomes & Mol PhLAM, F-59655 Villeneuve Dascq, France. TOTAL Oil Co, Pau, France. C2 IFREMER, FRANCE IFREMER, FRANCE UNIV LILLE, FRANCE TOTAL, FRANCE SI BREST SE PDG-REM-GM-LGM PDG-REM-EEP-LEP PDG-REM-GM-LES PDG-REM-EEP-LMEE PDG-REM-GM-CTDI IN WOS Ifremer jusqu'en 2018 copubli-france copubli-univ-france IF 2.469 TC 16 TU Centre national de la recherche scientifique Université Lille 1 - Sciences technologies Université du Littoral Côte d'Opale UR https://archimer.ifremer.fr/doc/00139/24981/23102.pdf LA English DT Article CR ERIG 3D NERIS 1 NERIS 2 BO Pourquoi pas ? Le Suroît L'Atalante DE ;Active pockmark;Anaerobic oxidation of methane;Gas hydrates;Carbonates;Seismic surveys;Fault system;U/Th dating AB A joint industrial project with IFREMER and Total provides insights into the tectonic setting and the geochemistry of a large active pockmark offshore W-Africa in the Niger Delta. The study combines both geophysical (seismic) and geochemical data to infer the dynamics of a 300 m wide pockmark located at 667 m water depth. Two Calypso cores, one at the centre and one outside the pockmark, along with three box-cores, two inside the pockmark and one outside, were collected to study the geochemistry of gas hydrates, carbonates and pore waters. Two seismic lines, a 3D high resolution random line and a 2D high resolution seismic line, provide a good description of the plumbing of the system. The integrated results depict a very active pockmark characterized by several gas charged-bodies, a well identified BSR marking a hydrate accumulation zone, charged from deeper sources via a network of faults. Hydrates and carbonate concretions have been detected inside the pockmark while only the latter has been found outside. The hydrate analyses show that the hydrate-forming gases are of thermogenic origin, albeit overwhelmingly composed of methane. Pore-water analyses reveal the occurrence of anaerobic oxidation of methane coupled with sulphate reduction at shallow depth (∼200 cm). The chloride concentration profile exhibits both values lower than that of seawater which is inherent to hydrate dissociation after core recovery and positive anomalies (values 7% higher than that of seawater background) at the lowermost part of the core. The latter evidence suggests current or recent hydrate formation at this area. The carbonate dating provides additional temporal information and indicates that this pockmark has been active since ∼21 kyr. PY 2013 PD MAY SO Marine And Petroleum Geology SN 0264-8172 PU Elsevier Sci Ltd VL 43 UT 000318831400019 BP 297 EP 309 DI 10.1016/j.marpetgeo.2013.01.008 ID 24981 ER EF