FN Archimer Export Format PT J TI The fate of river organic carbon in coastal areas: A study in the Rhone River delta using multiple isotopic (delta C-13, Delta C-14) and organic tracers BT AF CATHALOT, Cecile RABOUILLE, Christophe TISNERAT-LABORDE, N. TOUSSAINT, Flora KERHERVE, P. BUSCAIL, R. LOFTIS, K. SUN, M. -Y. TRONCZYNSKI, Jacek AZOURY, S. LANSARD, Bruno TREIGNIER, CLAIRE PASTOR, L. TESI, T. AS 1:1;2:1;3:1;4:1;5:2,3;6:2,3;7:4;8:4;9:5;10:;11:1;12:1;13:6;14:7,8; FF 1:;2:;3:;4:;5:;6:;7:;8:;9:PDG-RBE-BE-LBCO;10:;11:;12:;13:;14:; C1 UVSQ, CNRS, CEA, Lab Sci Climat & Environm, Gif Sur Yvette, France. CNRS, Ctr Format & Rech Environm Mediterraneens, UMR 5110, F-66860 Perpignan, France. Univ Perpignan, Ctr Format & Rech Environm Mediterraneens, UMR 5110, F-66860 Perpignan, France. Univ Georgia, Dept Marine Sci, Athens, GA 30602 USA. IFREMER, Lab Biogeochim Contaminants Organ, Nantes, France. Univ Paris 07, Lab Geochim Eaux, Paris, France. ISMAR CNR UOS Bologna, Ist Sci Marine, I-40129 Bologna, Italy. Stockholm Univ, Inst Appl Environm Res ITM, S-10691 Stockholm, Sweden. C2 UNIV VERSAILLES, FRANCE CNRS, FRANCE UNIV PERPIGNAN, FRANCE UNIV GEORGIA, USA IFREMER, FRANCE UNIV PARIS 07, FRANCE ISMAR, ITALY UNIV STOCKHOLM, SWEDEN SI NANTES SE PDG-RBE-BE-LBCO IN WOS Ifremer jusqu'en 2018 copubli-france copubli-europe copubli-univ-france copubli-int-hors-europe IF 4.25 TC 58 TU Centre national de la recherche scientifique Université de Perpignan - Via Domitia UR https://archimer.ifremer.fr/doc/00157/26784/25673.pdf LA English DT Article CR CHACCRA-BENT1 CHACCRA-BENT2 CHACCRA_PLUME MINERCOT 2 RHOFIBENT RHOSOS RIOMAR1 RIOTECH BO Téthys II L'Europe Le Suroît AB A significant fraction of the global carbon flux to the ocean occurs in River-dominated Ocean Margins (RiOMar) although large uncertainties remain in the cycle of organic matter (OM) in these systems. In particular, the OM sources and residence time have not been well clarified. Surface (0-1 cm) and sub-surface (3-4 cm) sediments and water column particles (bottom and intermediate depth) from the Rhone River delta system were collected in June 2005 and in April 2007 for a multi-proxy study. Lignin phenols, black carbon (BC), proto-kerogen/BC mixture, polycyclic aromatic hydrocarbons (PAHs), carbon stable isotope (delta C-13(OC)), and radiocarbon measurements (delta C-14(OC)) were carried out to characterize the source of sedimentary organic material and to address degradation and transport processes. The bulk OM in the prodelta sediment appears to have a predominantly modern terrigenous origin with a significant contribution of modern vascular C-3 plant detritus (Delta C-14(OC) = 27.9 parts per thousand, delta C-13(OC) = -27.4 parts per thousand). In contrast, the adjacent continental shelf, below the river plume, seems to be dominated by aged OM (Delta C-14(OC) = -400 parts per thousand, delta C-13(OC) = -24.2 parts per thousand), and shows no evidence of dilution and/or replacement by freshly produced marine carbon. Our data suggest an important contribution of black carbon (50% of OC) in the continental shelf sediments. Selective degradation processes occur along the main dispersal sediment system, promoting the loss of a modern terrestrial OM but also proto-kerogen-like OM. In addition, we hypothesize that during the transport across the shelf, a long term resuspension/deposition loop induces efficient long term degradation processes able to rework such refractory-like material until the OC is protected by the mineral matrix of particles. PY 2013 PD OCT SO Geochimica Et Cosmochimica Acta SN 0016-7037 PU Pergamon-elsevier Science Ltd VL 118 UT 000324035800003 BP 33 EP 55 DI 10.1016/j.gca.2013.05.001 ID 26784 ER EF