FN Archimer Export Format
PT J
TI Accelerated ageing and lifetime prediction of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) in distilled water
BT 
AF DEROINE, Morgan
   LE DUIGOU, Antoine
   CORRE, Yves-Marie
   LE GAC, Pierre-Yves
   DAVIES, Peter
   CESAR, Guy
   BRUZAUD, Stephane
AS 1:1;2:1;3:1;4:2;5:2;6:3;7:1;
FF 1:;2:;3:;4:PDG-REM-RDT-LCSM;5:PDG-REM-RDT-LCSM;6:;7:;
C1 Univ Bretagne Sud, LIMATB, EA 4250, F-56100 Lorient, France.
   IFREMER, Ctr Bretagne, Marine Struct Grp, F-29280 Plouzane, France.
   Univ Bretagne Sud, SERPBIO, F-56321 Lorient, France.
C2 UBS, FRANCE
   IFREMER, FRANCE
   UBS, FRANCE
SI BREST
SE PDG-REM-RDT-LCSM
IN WOS Ifremer jusqu'en 2018
   copubli-france
   copubli-univ-france
IF 2.24
TC 42
UR https://archimer.ifremer.fr/doc/00203/31396/29785.pdf
LA English
DT Article
DE ;Poly(3-hydroxybutyrate-co-3-hydroxyvalerate);Accelerated ageing;Hydrothermal degradation;Lifetime prediction
AB Accelerated ageing was performed in distilled water at different temperatures (25, 30, 40 and 50°C) on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV), which is a biodegradable biopolymer, in order to estimate its lifetime in aqueous environment. In a first part, degradation mechanisms were followed by gravimetry, tensile tests and steric exclusion chromatography. Both immersion and relative humidity have been examined. In a second part, the strain at break was used as an indicator for lifetime prediction with an Arrhenius extrapolation. The study revealed the presence of only one irreversible degradation mechanism, i.e. hydrolytic degradation, which is temperature dependant. So, within the approach assumptions, the lifetime in distilled water of PHBV following Arrhenius behaviour can be predicted.
PY 2014
PD OCT
SO Polymer Testing
SN 0142-9418
PU Elsevier Sci Ltd
VL 39
UT 000343384100011
BP 70
EP 78
DI 10.1016/j.polymertesting.2014.07.018
ID 31396
ER

EF