FN Archimer Export Format PT J TI Flood inputs in a Mediterranean coastal zone impacted by a large urban area: Dynamic and fate of trace metals BT AF Oursel, B. Garnier, C. Zebracki, Mathilde Durrieu, G. Pairaud, Ivane Omanović, D. Cossa, Daniel Lucas, Yves AS 1:1;2:1;3:2,3;4:1;5:2;6:4;7:2,5;8:1; FF 1:;2:;3:PDG-ODE-LER-LERPAC;4:;5:PDG-ODE-LITTORAL-LERPAC;6:;7:PDG-RBE-BE-LBCM;8:; C1 Université de Toulon, PROTEE, EA 3819, 83957 La Garde, France IFREMER, Centre de Méditerranée, Laboratoire Environnement Ressources Provence-Azur-Corse, BP 330, Zone Portuaire de Brégaillon, 83507 La Seyne-sur-Mer, France IRSN, Laboratoire d'études radioécologiques en milieu continental et marin, CEN Cadarache, 13115 Saint Paul lez Durance, France Ruđer Bošković Institute, Center for Marine and Environmental Research, PO Box 180, 10002 Zagreb, Croatia ISTerre, Université J. Fourier, BP 53, 38041 Grenoble, France C2 UNIV TOULON, FRANCE IFREMER, FRANCE IRSN, FRANCE RUDER BASKOVIC INST, CROATIA UNIV GRENOBLE, FRANCE SI TOULON SE PDG-ODE-LER-LERPAC PDG-ODE-LITTORAL-LERPAC PDG-RBE-BE-LBCM IN WOS Ifremer jusqu'en 2018 copubli-france copubli-europe copubli-univ-france TC 18 UR https://archimer.ifremer.fr/doc/00206/31761/30171.pdf LA English DT Article DE ;WWTP;metals contamination;coastal zone;flood events;Mediterranean Sea;small rivers AB Trace elements and organic carbon inputs to the Mediterranean sea from an urbanized area (Marseille city) were studied and characterized during flood events. Inputs were brought to the sea by two small coastal rivers whose waters were mixed together and also with treated wastewaters (TWW) just before discharge. The monitoring of the rivers during flood events showed the high temporal dynamics of water flow, suspended particulate matter (SPM), organic carbon and trace metals concentrations, typical of small coastal Mediterranean rivers and requiring an appropriate sampling strategy. Dissolved/particulate partition coefficient (log Kd) in rivers during floods remained quasi-constant for a given trace element, but differed from one element to another according to their affinity toward particles. Because of high SPM concentrations, trace elements were mainly brought to the sea during floods as particles, despite a weaker affinity for particles when compared to baseflow conditions for all studied elements but Pb. If the contribution of TWW dominated the elements baseflow discharge to the coastal zone, rivers outweighed during floods. When discharged to the sea, most trace elements underwent partial desorption in the salinity gradient, especially at highest salinity. Laboratory desorption experiments results were consistent with field data and showed slower desorption kinetics than in baseflow conditions, suggesting that trace elements desorption rates from particles are slower than sedimentation rates. With regard to heavy particles, it results in a potential impact of the sediment on benthic organisms and a possible further desorption after sediment resuspension events. With regard to light particles, it results possible additional desorption during offshore transport. PY 2014 PD DEC SO Marine Chemistry SN 03044203 PU Elsevier BV VL 167 UT 000345805700006 BP 44 EP 56 DI 10.1016/j.marchem.2014.08.005 ID 31761 ER EF