FN Archimer Export Format PT J TI Concentrations and fractionation of carbon, iron, sulfur, nitrogen and phosphorus in mangrove sediments along an intertidal gradient (semi-arid climate, New Caledonia) BT AF DEBORDE, Jonathan MARCHAND, Cyril MOLNAR, Nathalie DELLA PATRONA, Luc MEZIANE, Tarik AS 1:1;2:1;3:1,2;4:3;5:2; FF 1:;2:;3:;4:PDG-RBE-LEADNC;5:; C1 UMR 7590 IMPMC, UR 206, IRD, F-98848 New Caledonia, France. UMR BOREA 7208 CNRS MNHN UPMC IRD UCBN, Museum Natl Hist Nat, F-75231 Paris 05, France. Ctr IRD, Ifremer, Dept Lagons Ecosyst & Aquaculture Durable LEAD NC, Noumea, New Caledonia. C2 IRD, FRANCE MNHN, FRANCE IFREMER, FRANCE SI NOUMEA SE PDG-RBE-LEADNC IN WOS Ifremer jusqu'en 2018 copubli-france copubli-p187 IF 2.744 TC 36 UR https://archimer.ifremer.fr/doc/00251/36252/34802.pdf LA English DT Article DE ;mangrove;zonation;biogeochemistry;New Caledonia AB In mangrove ecosystems, strong reciprocal interactions exist between plant and substrate. Under semi-arid climate, Rhizophora spp. are usually predominant, colonizing the seashore, and Avicennia marina develops at the edge of salt-flats, which is the highest zone in the intertidal range. Along this zonation, distribution and speciation of C, Fe, S, N, and P in sediments and pore-waters were investigated. From the land-side to the sea-side of the mangrove, sediments were characterized by I/ increase in: (i) water content; (ii) TOC; (iii) mangrove-derived OM; II/ and decrease in: (i) salinity; (ii) redox; (iii) pH; (iv) solid Fe and solid P. Beneath Avicennia and Rhizophora, TS accumulated at depth, probably as a result of reduction of iron oxides and sulfate. The loss of total Fe observed towards the sea-side may be related to sulfur oxidation and to more intense tidal flushing of dissolved components. Except the organic forms, dissolved N and P concentrations were very low beneath Avicennia and Rhizophora stands, probably as a result of their uptake by the root systems. However, in the unvegetated salt-flat, NH4+ can accumulate in organic rich and anoxic layers. This study shows: (i) the evolution of mangrove sediment biogeochemistry along the intertidal zone as a result of the different duration of tidal inundation and organic enrichment; and (ii) the strong links between the distribution and speciation of the different elements. PY 2015 PD MAR SO Journal Of Marine Science And Engineering SN 2077-1312 PU Mdpi VL 3 IS 1 UT 000435663200003 BP 52 EP 72 DI 10.3390/jmse3010052 ID 36252 ER EF