FN Archimer Export Format PT J TI Hydrogen peroxide in the marine boundary layer over the South Atlantic during the OOMPH cruise in March 2007 BT AF FISCHER, H. POZZER, A. SCHMITT, T. JOECKEL, P. KLIPPEL, T. TARABORRELLI, D. LELIEVELD, J. AS 1:1;2:1;3:1;4:2;5:1;6:1;7:1; FF 1:;2:;3:;4:;5:;6:;7:; C1 Max Planck Inst Chem, Dept Atmospher Chem, Mainz, Germany. Deutsch Zentrum Luft & Raumfahrt DLR, Inst Phys Atmosphare, Oberpfaffenhofen, Germany. C2 MAX PLANCK INST, GERMANY DLR, GERMANY IN DOAJ IF 5.114 TC 17 UR https://archimer.ifremer.fr/doc/00289/40026/39252.pdf https://archimer.ifremer.fr/doc/00289/40026/81228.pdf LA English DT Article CR VT 88 / OOMPH-1 - MD 160 / OOMPH BO Marion Dufresne AB In the OOMPH (Ocean Organics Modifying Particles in both Hemispheres) project a ship measurement cruise took place in the late austral summer from 01 to 23 March 2007. The French research vessel Marion Dufresne sailed from Punta Arenas, Chile (70.85A degrees W, 53.12A degrees S), to R,union island (55.36A degrees E, 21.06A degrees S) across the South Atlantic Ocean. In situ measurements of hydrogen peroxide, methylhydroperoxide and ozone were performed and are compared to simulations with the atmospheric chemistry global circulation model EMAC (ECHAM/MESSy Atmospheric Chemistry). The model generally reproduces the measured trace gas levels, but it underestimates hydrogen peroxide mixing ratios at high wind speeds, indicating too-strong dry deposition to the ocean surface. An interesting feature during the cruise is a strong increase of hydrogen peroxide, methylhydroperoxide and ozone shortly after midnight off the west coast of Africa due to an increase in the boundary layer height, leading to downward transport from the free troposphere, which is qualitatively reproduced by the model. PY 2015 PD JUL SO Atmospheric Chemistry And Physics SN 1680-7316 PU Copernicus Gesellschaft Mbh VL 15 IS 12 UT 000357117500028 BP 6971 EP 6980 DI 10.5194/acp-15-6971-2015 ID 40026 ER EF