FN Archimer Export Format PT J TI Variability of alkalinity and the alkalinity-salinity relationship in the tropical and subtropical surface ocean BT AF JIANG, Zong-Pei TYRRELL, Toby HYDES, David J. DAI, Minhan HARTMAN, Susan E. AS 1:1,2;2:1;3:1;4:3;5:1; FF 1:;2:;3:;4:;5:; C1 Univ Southampton, Natl Oceanog Ctr, Southampton, Hants, England. Zhejiang Univ, Ocean Coll, Hangzhou 310003, Zhejiang, Peoples R China. Xiamen Univ, State Key Lab Marine Environm Sci, Xiamen, Peoples R China. C2 UNIV SOUTHAMPTON, UK UNIV ZHEJIANG, CHINA UNIV XIAMEN, CHINA IF 3.965 TC 60 UR https://archimer.ifremer.fr/doc/00292/40349/38934.pdf https://archimer.ifremer.fr/doc/00292/40349/38935.docx https://archimer.ifremer.fr/doc/00292/40349/38936.tif https://archimer.ifremer.fr/doc/00292/40349/38937.tif LA English DT Article CR OISO 8 OISO1 OISO2 OISO3-NIVMER98 OISO4 (VT 46) OISO5 (VT 49) VT 105 / OISO 17 VT 108 / OISO-18 VT 114 / OISO-19 VT 117 / OISO-20 VT 120 / OISO-21 VT 127 / OISO-22 VT 136 / OISO-23 VT 51 / OISO 6 VT 57 / OISO 9 VT 60 / CARAUS - OISO 10 VT 62 / CARAUS - OISO 11 VT 79 / OISO 12 VT 80 / OISO 13 VT 81 / OISO 14 VT 85 / OISO 15 VT 94 / OISO 16 BO Marion Dufresne AB The variability of total alkalinity (TA) and its relationship with salinity in the tropical and subtropical surface ocean were examined using data collected in various marine environments from a ship of opportunity. In the open ocean regions of the Atlantic, Pacific, and Indian Oceans, sea surface TA variability was observed to be mainly controlled by the simple dilution or concentration (SDC) effect of precipitation and evaporation, and the measured concentrations of TA agreed well with those predicted from salinity and temperature. Non-SDC changes in alkalinity in ocean margins and inland seas were examined by comparing the salinity-normalized alkalinity with that of the open ocean end-member. Non-SDC alkalinity additions to the western North Atlantic margin, eastern North Pacific margin, and Mediterranean Sea were identified, which mainly resulted from river inputs and shelf currents. In contrast, removal of TA through formation and sedimentation of calcium carbonate was observed to be an important control in the Red Sea. The concentration of the river end-member can only be reliably derived from the y intercept of TA-S regression (TA(S0)) in river-dominated systems such as estuaries and river plumes. In coastal regions where other processes (evaporation, shelf currents, upwelling, calcification, etc.) are more influential, TAS0 can significantly deviate from the river water concentration and hence be an unreliable indicator of it. Negative values of TAS0 can result from non-SDC TA removal at the low salinity end (relative to the salinity of the oceanic end-member) and/or non-SDC TA addition at high salinities (as occurs in the Mediterranean Sea). PY 2014 PD JUN SO Global Biogeochemical Cycles SN 0886-6236 PU Amer Geophysical Union VL 28 IS 7 UT 000340609800007 BP 729 EP 742 DI 10.1002/2013GB004678 ID 40349 ER EF