FN Archimer Export Format PT J TI Processes determining the marine alkalinity and calcium carbonate saturation state distributions BT AF CARTER, B. R. TOGGWEILER, J. R. KEY, R. M. SARMIENTO, J. L. AS 1:1;2:2;3:1;4:1; FF 1:;2:;3:;4:; C1 Princeton Univ, Atmospher & Ocean Sci Program, Princeton, NJ 08544 USA. NOAA, Geophys Fluid Dynam Lab, Princeton, NJ 08542 USA. C2 UNIV PRINCETON, USA NOAA, USA IN DOAJ IF 3.978 TC 31 UR https://archimer.ifremer.fr/doc/00292/40351/38922.pdf https://archimer.ifremer.fr/doc/00292/40351/38923.zip https://archimer.ifremer.fr/doc/00292/40351/71289.pdf https://archimer.ifremer.fr/doc/00292/40351/71290.zip LA English DT Article CR OISO 8 OISO1 OISO2 OISO3-NIVMER98 OISO4 (VT 46) OISO5 (VT 49) VT 105 / OISO 17 VT 108 / OISO-18 VT 114 / OISO-19 VT 117 / OISO-20 VT 120 / OISO-21 VT 127 / OISO-22 VT 136 / OISO-23 VT 51 / OISO 6 VT 57 / OISO 9 VT 60 / CARAUS - OISO 10 VT 62 / CARAUS - OISO 11 VT 79 / OISO 12 VT 80 / OISO 13 VT 81 / OISO 14 VT 85 / OISO 15 VT 94 / OISO 16 BO Marion Dufresne AB We introduce a composite tracer for the marine system, Alk*, that has a global distribution primarily determined by CaCO3 precipitation and dissolution. Alk* is also affected by riverine alkalinity from dissolved terrestrial carbonate minerals. We estimate that the Arctic receives approximately twice the riverine alkalinity per unit area as the Atlantic, and 8 times that of the other oceans. Riverine inputs broadly elevate Alk* in the Arctic surface and particularly near river mouths. Strong net carbonate precipitation results in low Alk* in subtropical gyres, especially in the Indian and Atlantic oceans. Upwelling of dissolved CaCO3-rich deep water elevates North Pacific and Southern Ocean Alk*. We use the Alk* distribution to estimate the variability of the calcite saturation state resulting from CaCO3 cycling and other processes. We show that regional differences in surface calcite saturation state are due primarily to the effect of temperature differences on CO2 solubility and, to a lesser extent, differences in freshwater content and air-sea disequilibria. The variations in net calcium carbonate cycling revealed by Alk* play a comparatively minor role in determining the calcium carbonate saturation state. PY 2014 PD DEC SO Biogeosciences SN 1726-4170 PU Copernicus Gesellschaft Mbh VL 11 IS 24 UT 000347959800012 BP 7349 EP 7362 DI 10.5194/bg-11-7349-2014 ID 40351 ER EF