FN Archimer Export Format PT J TI Natural Degradation and Biodegradation of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) in Liquid and Solid Marine Environments BT AF DEROINE, Morgan CESAR, Guy LE DUIGOU, Antoine DAVIES, Peter BRUZAUD, Stephane AS 1:1,2,3;2:2;3:1;4:3;5:1; FF 1:;2:;3:;4:PDG-REM-RDT-LCSM;5:; C1 Univ Bretagne Sud, EA 4250, LIMATB, F-56100 Lorient, France. Univ Bretagne Sud, SERPBIO, F-56321 Lorient, France. IFREMER, Marine Struct Grp, Ctr Bretagne, F-29280 Plouzane, France. C2 UBS, FRANCE UBS, FRANCE IFREMER, FRANCE SI BREST SE PDG-REM-RDT-LCSM IN WOS Ifremer jusqu'en 2018 copubli-france copubli-univ-france IF 1.969 TC 61 UR https://archimer.ifremer.fr/doc/00296/40735/42020.pdf LA English DT Article DE ;PHBV;Natural ageing;Degradation;Biodegradation;Seawater AB In this study, natural degradation and biodegradation of poly(3-hydroxybuyrate-co-3-hydroxyvalerate) (PHBV) films were followed in different marine environments. First of all, ageing of PHBV films was investigated in natural seawater for 180 days and degradation was followed by means of weight loss measurements, scanning electron microscopy (SEM), differential scanning calorimetry and steric exclusion chromatography. In a second part, biodegradation tests were performed on PHBV powder, by following carbon dioxide (CO2) release(,) to highlight the PHBV bioassimilation of marine microorganisms. Three different marine environments were considered for biodegradation tests: a solid inoculum with foreshore sand, a solid-liquid inoculum with sand and seawater and a liquid inoculum with seawater. In the latter, a biofilm was added to study the influence of microorganisms on biodegradation kinetics. The films aged under natural conditions show a large loss of weight after 180 days in immersion, around 36 %, confirmed by SEM pictures which show an increase of the surface erosion and a decrease of the sample thickness. Microorganisms' attack occurred as suggested by CO2 release during biodegradation tests, whatever the environment studied. PY 2015 PD DEC SO Journal Of Polymers And The Environment SN 1566-2543 PU Springer/plenum Publishers VL 23 IS 4 UT 000363984000008 BP 493 EP 505 DI 10.1007/s10924-015-0736-5 ID 40735 ER EF