FN Archimer Export Format PT J TI Particles transformation in estuaries: Fe, Mn and REE signatures through the Loire Estuary BT AF THIBAULT DE CHANVALON, A. METZGER, E. MOURET, A. KNOERY, Joel CHIFFOLEAU, Jean-Francois BRACH-PAPA, Christophe AS 1:1,2;2:1;3:1;4:2;5:2;6:2; FF 1:;2:;3:;4:PDG-RBE-BE-LBCM;5:PDG-RBE-BE;6:PDG-ODE-LITTORAL-LERPAC; C1 Univ Angers, CNRS, UMR 6112, LPG,BIAF, F-49045 Angers, France. IFREMER, LBCM, Rue Ile Yeu, F-44300 Nantes, France. C2 UNIV ANGERS, FRANCE IFREMER, FRANCE SI NANTES TOULON SE PDG-RBE-BE-LBCM PDG-RBE-BE PDG-ODE-LITTORAL-LERPAC IN WOS Ifremer jusqu'en 2018 copubli-france copubli-univ-france IF 1.888 TC 9 UR https://archimer.ifremer.fr/doc/00367/47848/47935.pdf LA English DT Article CR CAMELIA AB During their transfer across estuaries, particles endure numerous cycles of deposition-resuspension accompanied by several redox oscillations. These oscillations are likely to modify the particles content of redox sensitive metals such as Fe, Mn and two rare earth elements (REE): Ce and Eu. The present paper focuses on the fate of particles originating from the Loire Estuary by the study of chemical composition changes of both total and ascorbate-extracted phases. Transformations of particles buried in the sediment are estimated from sediment cores sampled in an estuarine intertidal mudflat Changes affecting particles that are transferred to the ocean are evaluated by comparing the composition of suspended particulate matter (SPM) from riverine time series to coastal marine SPM. Our results show an important decrease of SPM iron content corresponding to a loss of 14.3% of total iron. However, no iron storage was observed in the intertidal mudflat. Manganese is probably also lost during the transfer but the riverine temporal variability prevents its quantification. The similarity of Ce and Eu signatures between highly concentrated SPM and sedimentary particles suggests that most estuarine transformations are probably induced by early diagenesis during deposition (and frequently anoxic) periods. PY 2016 PD DEC SO Journal Of Sea Research SN 1385-1101 PU Elsevier Science Bv VL 118 UT 000390826000009 BP 103 EP 112 DI 10.1016/j.seares.2016.11.004 ID 47848 ER EF