FN Archimer Export Format PT J TI Spectrophotometric determination of phosphate in matrices from sequential leaching of sediments BT AF ANSCHUTZ, Pierre DEBORDE, Jonathan AS 1:1;2:1; FF 1:;2:; C1 Univ Bordeaux, CNRS, UMR EPOC 5805, Talence, France. C2 UNIV BORDEAUX, FRANCE IF 1.992 TC 29 UR https://archimer.ifremer.fr/doc/00375/48616/49431.pdf LA English DT Article BO Planula IV AB The speciation of Phosphorus (P) in geologic materials can inform diverse investigations in such as aquatic biogeochemistry, soil sciences, and paleo-oceanography. Here, we describe in detail a set of sequential extraction schemes to measure P concentrations from several operationally defined phases: pore water, exchangeable or loosely sorbed P, Fe-bound P, P associated with biogenic apatite, P associated with authigenic apatite and carbonate forms, P associated with detrital apatite and inorganic forms, and organic P. The two benefits of the procedures we describe compared to prior methodological studies are: (1) fast, simple and inexpensive colorimetric methods have been developed for P determination in all the different matrices; and (2) the Fe-bound phosphorus pool is separated into two fractions, allowing the P associated with most reactive Fe-fraction to be distinguished from P bound to the remainder of the Fe-oxides. Adaptations of these procedures to optimize the characterization of P pools in a range of material types are also outlined. PY 2016 PD APR SO Limnology And Oceanography-methods SN 1541-5856 PU Wiley-blackwell VL 14 IS 4 UT 000374774300002 BP 245 EP 256 DI 10.1002/lom3.10085 ID 48616 ER EF