FN Archimer Export Format PT J TI Sources and exchanges of mercury in the waters of the Northwestern Mediterranean margin BT AF COSSA, Daniel DE MADRON, Xavier Durrieu SCHAFER, Jorg GUEDRON, Stephane MARUSCZAK, Nicolas CASTELLE, Sabine NAUDIN, Jean-Jacques AS 1:1,2;2:3;3:4;4:2;5:1;6:1;7:5; FF 1:PDG-RBE-BE-LBCM;2:;3:;4:;5:;6:;7:; C1 IFREMER, Mediterranean Ctr, BP 330, F-83507 La Seyne Sur Mer, France. Univ Grenoble Alpes, ISTerre, BP 53, F-38041 Grenoble, France. Univ Perpignan, CNRS CEFREM, 52 Ave P Alduy, F-66860 Perpignan, France. Univ Bordeaux, EPOC, F-33615 Pessac, France. Univ P&M Curie, Lobb, F-66651 Banyuls Sur Mer, France. C2 IFREMER, FRANCE UNIV GRENOBLE ALPES, FRANCE UNIV PERPIGNAN, FRANCE UNIV BORDEAUX, FRANCE UNIV PARIS 06, FRANCE SI TOULON SE PDG-RBE-BE-LBCM IN WOS Ifremer jusqu'en 2018 copubli-france copubli-univ-france IF 3.245 TC 12 UR https://archimer.ifremer.fr/doc/00384/49563/50055.pdf LA English DT Article CR BIOPRHOFI CASCADE BO Le Suroît L'Atalante DE ;Mercury;Ocean margin;Coastal area;Mediterranean AB Ocean margins are focal regions in terms of mercury (Hg) exchanges between the continent and the open sea. The aim of this paper is to describe the distribution and partition of Hg between the gaseous, dissolved and particulate phases in the waters of the Northwestern Mediterranean (NWM) margin, in order to assess the Hg sources and exchanges within the continuum between the continental shelf (Gulf of Lions) and the open sea (Northern Gyre). Mean (± standard deviation) of total Hg species (HgT) concentrations in unfiltered water samples were 1.52 ± 1.00 pmol L-1 (n=36) in the inner shelf, 1.09 ± 0.15 pmol L-1 (n=30) along the slope, and 1.10 ± 0.13 pmol L-1 (n=99) in the Northern Gyre. The dissolved phase (<0.45µm) average concentrations were 0.80 ± 0.47 pmol L-1 (n=37) in the inner shelf, 0.93 ± 0.20 pmol L-1 (n=4) along the slope and 0.84 ± 0.10 (n=20) pmol L-1 in the Northern Gyre. The particulate fraction of Hg decreased very strongly seaward from around 60% on the shelf to 10-25% above the Northern Gyre. Very low dissolved HgT concentrations occurred in the inner shelf water, consistent with the results of incubation experiments, which demonstrated that shelf water is very efficient in both production and release of dissolved gaseous Hg into the atmosphere. In the North Gyre waters column HgT presents a distribution pattern inverse to that of dissolved oxygen, and a slight Hg enrichment in the deep layer (Western Mediterranean Deep Water). The Hg from the open sea water is the largest Hg input to the Gulf of Lions (∼5.7 kmol yr-1), whereas inputs from the riverine source account for ∼3.4 kmol yr-1 and atmospheric deposition for less than 0.5 kmol yr-1. The Hg accumulated in the sediments of the shelf is ∼4.5 kmol yr-1, including 0.6-1.7 kmol yr-1 in the Rhône prodelta sediments. The evasion to the atmosphere represents a Hg flux of ∼2.6 kmol yr-1. PY 2018 PD APR SO Progress In Oceanography SN 0079-6611 PU Pergamon-elsevier Science Ltd VL 163 UT 000434004400015 BP 172 EP 183 DI 10.1016/j.pocean.2017.05.002 ID 49563 ER EF