FN Archimer Export Format PT J TI On the early fate of hydrothermal iron at deep-sea vents: A reassessment after in situ filtration BT AF WAELES, Mathieu COTTE, Laura PERNET-COUDRIER, Benoit CHAVAGNAC, V. CATHALOT, Cecile LELEU, T. LAES-HUON, Agathe PERHIRIN, Antoine RISO, R. D. SARRADIN, Pierre-Marie AS 1:1;2:2;3:1;4:3;5:4;6:3;7:5;8:2;9:1;10:2; FF 1:;2:PDG-REM-EEP-LEP;3:;4:;5:PDG-REM-GM-LCG;6:;7:PDG-REM-RDT-LDCM;8:PDG-REM-EEP-LEP;9:;10:PDG-REM-EEP; C1 Univ Bretagne Occidental, LEMAR UMR CNRS 6539, IUEM, Plouzane, France. IFREMER, Environm Profond DEEP REM, ZI Pointe Diable, Plouzane, France. Univ Toulouse, Lab Geosci Environm Toulouse, GET UMR CNRS 5563, Toulouse, France. IFREMER, Geochim & Metallogenie GM REM, Plouzane, France. IFREMER, Lab Detect Capteurs & Mesures REM RDT, Plouzane, France. C2 UBO, FRANCE IFREMER, FRANCE UNIV TOULOUSE, FRANCE IFREMER, FRANCE IFREMER, FRANCE SI BREST SE PDG-REM-EEP-LEP PDG-REM-GM-LCG PDG-REM-RDT-LDCM PDG-REM-EEP UM LEMAR IN WOS Ifremer jusqu'en 2018 copubli-france copubli-univ-france IF 4.339 TC 17 UR https://archimer.ifremer.fr/doc/00388/49944/50522.pdf https://archimer.ifremer.fr/doc/00388/49944/50523.pdf https://archimer.ifremer.fr/doc/00388/49944/50524.pdf https://archimer.ifremer.fr/doc/00388/49944/50525.xlsx LA English DT Article CR BICOSE MOMARSAT2014 MOMARSAT2015 BO Pourquoi pas ? DE ;hydrothermal;iron;sulfide;venting;filtration;precipitation AB Deep-sea hydrothermal venting is now recognized as a major source of iron (Fe), an essential trace element that controls marine productivity. However, the reactions occurring during dispersal from buoyant plumes to neutrally buoyant hydrothermal plumes are still poorly constrained. Here we report for the first time on the dissolved-particulate partition of Fe after in situ filtration at the early stage of mixing at different hydrothermal discharges, i.e., Lucky Strike (37 degrees N), TAG (26 degrees N), and Snakepit (23 degrees N) on the Mid-Atlantic Ridge. We found that hydrothermal iron is almost completely preserved (>90%) in the dissolved fraction, arguing for low iron-bearing sulfide precipitation of iron in basalt-hosted systems with low Fe:H2S ratios. This result can only be explained by a kinetically limited formation of pyrite. The small part of Fe being precipitated as sulfides in the mixing gradient (<10%) is restricted to the inclusion of Fe in minerals of high Cu and Zn content. We also show that secondary venting is a source of Fe-depleted hydrothermal solutions. These results provide new constrains on Fe fluxes from hydrothermal venting. PY 2017 PD MAY SO Geophysical Research Letters SN 0094-8276 PU Amer Geophysical Union VL 44 IS 9 UT 000402143700032 BP 4233 EP 4240 DI 10.1002/2017GL073315 ID 49944 ER EF