FN Archimer Export Format PT J TI Investigation of aromatic hydrocarbon inclusion into cyclodextrins by Raman spectroscopy and thermal analysis BT AF TIJUNELYTE, Inga DUPONT, Nathalie MILOSEVIC, Irena BARBEY, Carole RINNERT, Emmanuel LIDGI-GUIGUI, Nathalie GUENIN, Erwann DE LA CHAPELLE, Marc Lamy AS 1:1;2:1;3:1;4:1;5:2;6:1;7:1;8:1; FF 1:;2:;3:;4:;5:PDG-REM-GM-LCG;6:;7:;8:; C1 Univ Paris 13, Lab CSPBAT UMR CNRS 7244, UFR Sante Med Biol Humaine, 74 Rue Marcel Cachin, F-93017 Bobigny, France. IFREMER, Lab Detect Capteurs & Mesures, Unite Rech & Dev Technol, CS10070, F-29280 Plouzane, France. C2 UNIV PARIS 13, FRANCE IFREMER, FRANCE SI BREST SE PDG-REM-GM-LCG IN WOS Ifremer jusqu'en 2018 copubli-france copubli-univ-france IF 2.8 TC 16 UR https://archimer.ifremer.fr/doc/00417/52845/53907.pdf LA English DT Article DE ;Raman spectroscopy;Thermogravimetric analysis;Cyclodextrin;Polyaromatic hydrocarbons;PAH;Host-guest complex AB Among various cavitand molecules, cyclodextrins are extensively studied due to their ability to form host-guest complexes with small hydrophobic molecules. Aiming to explore cyclodextrin implementation on the scopes related to the environmental pollution monitoring or remediation, extensive studies for understanding the cyclodextrin-based host-guest complex formation with selected targeted substances are conducted. In this context, two polycyclic aromatic hydrocarbons, naphthalene and fluoranthene as well as toluene as a member of volatile organic compounds, were studied regarding their ability to encapsulate into cyclodextrin cavities. Synthesised complexes were examined by thermogravimetric analysis combined with Raman spectroscopy. The obtained results demonstrated that the size between targeted molecules and the cyclodextrin cavities strongly correlates with its ability to engage in complexation. Thus, this latter parameter plays an important role in the inclusion complex formation as well as in the strength of the interaction between the molecules. PY 2017 PD DEC SO Environmental Science And Pollution Research SN 0944-1344 PU Springer Heidelberg VL 24 IS 35 UT 000417545800016 BP 27077 EP 27089 DI 10.1007/s11356-015-4361-6 ID 52845 ER EF