FN Archimer Export Format PT J TI Evolution of South Atlantic density and chemical stratification across the last deglaciation BT AF ROBERTS, Jenny GOTTSCHALK, Julia SKINNER, Luke C. PECK, Victoria L. KENDER, Sev ELDERFIELD, Henry WAELBROECK, Claire RIVEIROS, Natalia Vazquez HODELL, David A. AS 1:1,2;2:1;3:1;4:2;5:3,4;6:1;7:5;8:5;9:1; FF 1:;2:;3:;4:;5:;6:;7:;8:;9:; C1 Univ Cambridge, Dept Earth Sci, Godwin Lab Paleoclimate Res, Cambridge CB2 3EQ, England. British Antarctic Survey, Cambridge CB3 0ET, England. Univ Nottingham, Sch Geog, Ctr Environm Geochem, Nottingham NG7 2RD, England. British Geol Survey, Nottingham NG12 5GG, England. Domaine CNRS, Lab Sci Climat & Environm, F-91198 Gif Sur Yvette, France. C2 UNIV CAMBRIDGE, ENGLAND BRITISH ANTARCTIC SURVEY, ENGLAND UNIV NOTTINGHAM, ENGLAND BRITISH GEOL SURVEY, ENGLAND CNRS, FRANCE IF 9.661 TC 51 UR https://archimer.ifremer.fr/doc/00421/53276/54569.pdf https://archimer.ifremer.fr/doc/00421/53276/54570.pdf LA English DT Article CR MD 158 / LOGIPEV 2007 VT 90 / SOUC BO Marion Dufresne DE ;South Atlantic;density gradient;ocean stratification;last deglaciation;atmospheric CO2 AB Explanations of the glacial-interglacial variations in atmospheric pCO(2) invoke a significant role for the deep ocean in the storage of CO2. Deep-ocean density stratification has been proposed as a mechanism to promote the storage of CO2 in the deep ocean during glacial times. A wealth of proxy data supports the presence of a "chemical divide" between intermediate and deep water in the glacial Atlantic Ocean, which indirectly points to an increase in deep-ocean density stratification. However, direct observational evidence of changes in the primary controls of ocean density stratification, i.e., temperature and salinity, remain scarce. Here, we use Mg/Ca-derived seawater temperature and salinity estimates determined from temperature-corrected delta O-18 measurements on the benthic foraminifer Uvigerina spp. from deep and intermediate water-depth marine sediment cores to reconstruct the changes in density of sub-Antarctic South Atlantic water masses over the last deglaciation (i.e., 22-2 ka before present). We find that a major breakdown in the physical density stratification significantly lags the breakdown of the deep-intermediate chemical divide, as indicated by the chemical tracers of benthic foraminifer delta C-13 and foraminifer/coral C-14. Our results indicate that chemical destratification likely resulted in the first rise in atmospheric pCO(2), whereas the density destratification of the deep South Atlantic lags the second rise in atmospheric pCO(2) during the late deglacial period. Our findings emphasize that the physical and chemical destratification of the ocean are not as tightly coupled as generally assumed. PY 2016 PD JAN SO Proceedings Of The National Academy Of Sciences Of The United States Of America SN 0027-8424 PU Natl Acad Sciences VL 113 IS 3 UT 000368458800033 BP 514 EP 519 DI 10.1073/pnas.1511252113 ID 53276 ER EF