FN Archimer Export Format PT J TI Zinc isotopes as tracers of anthropogenic sources and biogeochemical processes in contaminated mangroves BT AF FERREIRA ARAUJO, Daniel MACHADO, Wilson WEISS, Dominik MULHOLLAND, Daniel S. GARNIER, Jeremie SOUTO-OLIVEIRA, Carlos E. BABINSKI, Marly AS 1:1,2,3;2:4;3:5;4:6;5:3;6:1;7:1; FF 1:PDG-RBE-BE-LBCM;2:;3:;4:;5:;6:;7:; C1 Univ Sao Paulo, Inst Geociencias, Rua Lago 562,Cidade Univ, Sao Paulo, Brazil. IFREMER, Lab Biogeochim Contaminants Metall, Ctr Atlant, F-44311 Nantes 3, France. Univ Brasilia, LMI OCE, IRD, Campus Darcy Ribeiro, Brasilia, DF, Brazil. Univ Fed Fluminense, Dept Geoquim, Campus Valonguinho, Niteroi, RJ, Brazil. Imperial Coll London, Earth Sci & Engn, London, England. Univ Fed Tocantins, Dept Quim Ambiental, Rua Badejos,Lote 7,Chacaras 69-72, Gurupi, Tocantins, Brazil. C2 UNIV SAO PAULO, BRAZIL IFREMER, FRANCE UNIV BRASILIA, BRAZIL UNIV FED FLUMINENSE, BRAZIL IMPERIAL COLL LONDON, UK UNIV FED TOCANTINS, BRAZIL SI NANTES SE PDG-RBE-BE-LBCM IN WOS Ifremer jusqu'en 2018 copubli-europe copubli-int-hors-europe copubli-sud IF 2.894 TC 28 UR https://archimer.ifremer.fr/doc/00440/55196/56660.pdf LA English DT Article DE ;Metal transition isotopes;Metal contamination;Mass spectrometry;Coastal ecosystems;Mangrove leaves AB Recent work has shown that variations in zinc (Zn) isotope ratios enable us to identify contamination sources in the terrestrial environment and uptake processes in higher plants. Here in this study, we demonstrate that this also holds true for mangrove forests, which play an important role in the biogeochemical cycling of metals in tropical coastal ecosystems and that are seriously threatened by anthropogenic pollution. To this end, we determined zinc concentration and isotope composition (expressed using the δ66Zn notation relative to the JMC 3-0749-L standard) in sediments and tree leaves collected from a mangrove close to Rio de Janeiro in Brazil. The δ66ZnJMC values of sediments vary between +0.36 and + 0.84‰ and fall on a mixing line between detrital terrestrial sources (characterized with δ66ZnJMC = +0.28 ± 0.12‰, 2σ) and metallurgical ore sources (δ66ZnJMC = +0.86‰ ±0.15‰, 2σ). Leaves of Laguncularia racemose, in contrast, showed δ66ZnJMC values ranging between +0.08 and + 0.23‰, suggesting that processes including uptake, translocation and bioavailability in the rhizosphere control the isotope composition of zinc in the mangrove plant. PY 2018 PD AUG SO Applied Geochemistry SN 0883-2927 PU Pergamon-elsevier Science Ltd VL 95 UT 000437294900003 BP 25 EP 32 DI 10.1016/j.apgeochem.2018.05.008 ID 55196 ER EF