FN Archimer Export Format PT J TI Polycyclic aromatic hydrocarbons in surface sediments of the mid-Adriatic and along the Croatian coast: Levels, distributions and sources BT AF MANDIC, Jelena TRONCZYNSKI, Jacek KUSPILIC, Grozdan AS 1:1,2;2:1;3:2; FF 1:;2:PDG-RBE-BE;3:; C1 IFREMER, Ctr Atlantique, Dept Ressources Biol & Environm, BP 21105, F-44311 Nantes 03, France. IOF, Setaliste I Mestrovica 63, Split 21000, Croatia. C2 IFREMER, FRANCE IOF, CROATIA SI NANTES SE PDG-RBE-BE-LBCO PDG-RBE-BE IN WOS Ifremer jusqu'en 2018 copubli-europe IF 5.714 TC 15 UR https://archimer.ifremer.fr/doc/00448/55965/57473.pdf https://archimer.ifremer.fr/doc/00448/55965/57474.pdf https://archimer.ifremer.fr/doc/00448/55965/57475.xml https://archimer.ifremer.fr/doc/00448/55965/57652.pdf LA English DT Article CR PERSMED 2 BO Antea DE ;Marine sediments;Polycyclic aromatic hydrocarbons (PAHs);Source profiles;Source apportionment;Source-receptor models AB This study provides contamination levels, distributions and source apportionment of PAHs in surface sediments in the mid-Adriatic and along the Croatian coast. Median summed concentrations of parent and alkyl-PAHs are circa 10 times lower in the off-shore transect stations of the mid-Adriatic (22.3 and 18.2 μg.kg−1 d.w.) than the ranges determined at the coastal stations, including those of Kaštela bay (227–331 and 11.7–197 μg.kg−1 d.w., respectively). The highest levels, circa 20 times higher, were found in Šibenik bay (median 6603 and 3051 μg.kg−1). The overall range of PAH concentrations spans more than 2000 times between the lowest and the highest contamination level. The geographical distributions reflect the presence of strong gradients at local and regional scales. A major factor influencing sedimentary PAH distributions at local scale appears to be the distance from their known continental and coastal upstream emission sites (urban, industrial, harbour …), whereas at regional scale, this distribution depends more on the routes of entry of PAHs into the study area. Two combustion and one petroleum model source profiles of PAHs were determined by alternative least square analysis. Benzo[b+j]fluoranthenes and fluoranthene/pyrene are compounds characterizing two pyrogenic sources respectively, while signatures of alkyl-substituted homologues (phenanthrenes/anthracenes, fluranthenes/pyrenes, chrysenes and dibenzothiophenes) delineate a petrogenic source profile. The quantitative apportionment of source contributions shows significant geographical differences, with a dominant petrogenic source found along the mid-Adriatic transect (approximately 74%) and in Kaštela bay (61%). In the coastal sediments about a fifty-fifty contamination mix is assigned to a petrogenic/pyrogenic source of PAHs (47% and 53% respectively), whereas in Šibenik bay a strong predominance is apportioned to the combustion compounds (81%). PY 2018 PD NOV SO Environmental Pollution SN 0269-7491 PU Elsevier Sci Ltd VL 242 IS Part A UT 000446150300056 BP 519 EP 527 DI 10.1016/j.envpol.2018.06.095 ID 55965 ER EF