TY - JOUR T1 - REE distribution and Nd isotope composition of estuarine waters and bulk sediment leachates tracing lithogenic inputs in eastern Canada A1 - Casse,Marie A1 - Montero-Serrano,Jean-Carlos A1 - St-Onge,Guillaume A1 - Poirier,André AD - Institut des sciences de la mer de Rimouski, Canada Research Chair in Marine Geology, Université du Québec à Rimouski, 310 allée des Ursulines, Rimouski, Québec G5L 3A1, Canada AD - GEOTOP Research Center, 201 Av. Président Kennedy, Montréal, Québec, Canada UR - https://doi.org/10.1016/j.marchem.2019.03.012 DO - 10.1016/j.marchem.2019.03.012 KW - Estuary and gulf of St. Lawrence KW - Rare earth element KW - Neodymium isotopes KW - Strontium isotopes KW - Particle scavenging KW - Sediment provenance KW - Estuarine processes N2 - The rare earth element (REE) concentrations and the neodymium (Nd) and strontium (Sr) isotope compositions of the detrital fraction and authigenic FeMn oxyhydroxide coatings of marine sediments may provide valuable information for better understanding the pathways of weathering inputs and estuarine and coastal exchange processes on different time scales. Here, we present the REE concentrations and 143Nd/144Nd (expressed in epsilon units, εNd) and 87Sr/86Sr ratios of detrital and authigenic (leached FeMn oxyhydroxides) fractions from sediment core-top samples and of estuarine water samples collected in the Estuary and Gulf of St. Lawrence (EGSL) and continental shelf off southeastern Canada. The REE distribution patterns, εNd values, and 87Sr/86Sr isotopic values from the detrital fraction allow for the discrimination of sediment from continental sources in the EGSL. Sediments in the Baie des Chaleurs and on the continental shelf, which have εNd values ranging from −14.3 to −16, 87Sr/86Sr values ranging from 0.72708 to 0.71475, and low La/Yb and Gd/Yb ratios, are mainly supplied by the early Paleozoic Appalachian Mountains. In contrast, sediments in the Laurentian and Esquiman channels (εNd = −18.7 to −21.8, 87Sr/86Sr = 0.72068 to 0.72607, and high La/Yb and Gd/Yb ratios) come from the Grenvillian metamorphic rocks in the Canadian Shield, and surface sediments on the southern Labrador Shelf (εNd = −28.7, 87Sr/86Sr = 0.73062, and high La/Yb and Gd/Yb ratios) mainly originate from the Hudson Strait and Baffin Bay. The εNd values obtained from estuarine water samples and bulk sediment leachates are unradiogenic, with values ranging between −18.9 and − 21.7 and between −16.1 and − 27.2, respectively. Based on these results and the dissolved REE concentrations, we speculate that salt-induced coagulation of colloidal matter, dissolution of lithogenic sediments from the adjacent continents (notably from the erosion of the Grenville Province on the North Shore), bottom scavenging within the nepheloid layer, and brine rejection during sea ice formation significantly influence the distribution of REEs and the authigenic εNd signal throughout the water column in the EGSL. Overall, our results both underscore the fact that caution must be exercised when interpreting authigenic εNd records due to bottom water-mass mixing in estuarine and coastal marine environments and highlight the potential of REE and NdSr isotope compositions in investigating changes in sediment sources and transport pathways in the EGSL. Y1 - 2019/04 PB - Elsevier BV JF - Marine Chemistry SN - 0304-4203 VL - 211 SP - 117 EP - 130 ID - 59708 ER -