FN Archimer Export Format
PT J
TI Thermal oxidation of Poly(dicyclopentadiene)– kinetic modeling of double bond consumption
BT 
AF Huang, Jing
   DAVID, Adelina
   Le Gac, Pierre Yves
   Lorthioir, Cedric
   Coelho, Cristina
   Richaud, Emmanuel
AS 1:1;2:2;3:2;4:3;5:4;6:1;
FF 1:;2:PDG-REM-RDT-LCSM;3:PDG-REM-RDT-LCSM;4:;5:;6:;
C1 Laboratoire PIMM, Arts et Métiers, CNRS, Cnam, HESAM Université, 151 Boulevard de l'Hôpital, F-75013, Paris, France
   IFREMER, Service Matériaux et Structures, Centre de Brest BP70, F-29280, Plouzané, France
   Sorbonne Université, CNRS, Collège de France, Laboratoire de Chimie de la Matière Condensée de Paris, LCMCP, 4 Place Jussieu, F-75005, Paris, France
   Sorbonne Université, CNRS, Institut des Matériaux de Paris Centre, FR 2482, F-75005, Paris, France
C2 ENSAM, FRANCE
   IFREMER, FRANCE
   UNIV PARIS 06, FRANCE
   UNIV PARIS 06, FRANCE
SI BREST
SE PDG-REM-RDT-LCSM
IN WOS Ifremer UPR
   copubli-france
   copubli-univ-france
IF 4.032
TC 18
UR https://archimer.ifremer.fr/doc/00502/61327/64899.pdf
LA English
DT Article
DE ;Polydicyclopentadiene;Thermal oxidation;Kinetic modeling;Crosslinking
AB This paper reports chemical changes that occur in polydicyclopentadiene during thermal oxidation at several temperatures and oxygen pressures. A particular attention was paid to the double bond consumption since these latter are associated with crosslinking and subsequent changes in mechanical properties. A kinetic model was derived from the experimental results. Its rate constants were assessed from the “inverse approach” based on their selective identification under specific ageing conditions (for example under oxygen excess). The resulting model satisfactorily describes both carbonyl formation and double bond consumption for a wide range of temperature and oxygen pressure for the first time. This can be exploited to predict the changes of local mechanical properties. 
PY 2019
PD AUG
SO Polymer Degradation And Stability
SN 0141-3910
PU Elsevier BV
VL 166
UT 000480377900026
BP 258
EP 271
DI 10.1016/j.polymdegradstab.2019.06.003
ID 61327
ER

EF