FN Archimer Export Format PT J TI Metal partitioning after in situ filtration at deep-sea vents of the Lucky Strike hydrothermal field (EMSO-Azores, Mid-Atlantic Ridge, 37°N) BT AF Cotte, Laura Chavagnac, V. Pelleter, Ewan Laës-Huon, A. Cathalot, Cecile Dulaquais, Gabriel Riso, Ricardo Sarradin, Pierre-Marie Waeles, Mathieu AS 1:1,2;2:3;3:4;4:5;5:4;6:1;7:1;8:2;9:1; FF 1:PDG-REM-EEP-LEP;2:;3:PDG-REM-GM-LCG;4:;5:PDG-REM-GM-LCG;6:;7:;8:PDG-REM-EEP;9:; C1 Univ Brest, CNRS, IRD, Ifremer, LEMAR, F-29280, Plouzane, France Laboratoire Environnement Profond (LEP/EEP/REM), Ifremer, ZI de La Pointe Du Diable, CS 10070, 29280, Plouzané, France Laboratoire Géosciences Environnement Toulouse, GET UMR-CNRS 5563, Université de Toulouse, 31400, Toulouse, France Laboratoire Cycle Géochimique et Ressources (LCG/GM/REM), Ifremer, ZI de La Pointe Du Diable, CS 10070, 29280, Plouzané, France Laboratoire Détection, Capteurs et Mesures (DCM/RDT/REM), Ifremer, ZI de La Pointe Du Diable, CS 10070, 29280, Plouzané, France C2 UBO, FRANCE IFREMER, FRANCE UNIV TOULOUSE, FRANCE IFREMER, FRANCE IFREMER, FRANCE SI BREST SE PDG-REM-EEP-LEP PDG-REM-GM-LCG PDG-REM-EEP UM LEMAR IN WOS Ifremer UPR WOS Cotutelle UMR copubli-france copubli-univ-france IF 2.955 TC 6 UR https://archimer.ifremer.fr/doc/00598/71060/93513.pdf LA English DT Article CR MOMARSAT : MONITORING THE MID ATLANTIC RIDGE MOMARSAT2014 MOMARSAT2015 MOMARSAT2016 BO Pourquoi pas ? L'Atalante DE ;Deep-sea vents;Hydrothermal;Metal;Mixing gradient;Precipitation;In-situ filtration AB Metal partitioning between the dissolved and particulate phases is still poorly constrained within the early mixing of hydrothermal fluids and deep seawater. In this study, in situ filtration has been used to collect early buoyant plume fluids. This has provided the unique opportunity to reassess precisely metal partitioning along the mixing gradient by limiting chemical exchange processes between the dissolved (<0.45 μm) and particulate (>0.45 μm) phases during sampling. We report on the partitioning of three major metals (Fe, Cu, Zn) in the early buoyant plume of six black and clear smokers from the Lucky Strike hydrothermal field (37°N, MAR; EMSO-Azores deep sea observatory). We show that chemical changes are limited in the warmest part of the plume [50–150°C, dMn > 40 μM; dilution factor (DF) of ~1–10 by NADW] as metal partitioning displays a chemical signature similar to the end-member one. However, as the dilution ratio between the hydrothermal fluid and North-Atlantic Deep-water (NADW) increases (4–50°C, dMn < 40 μM; DF of 10–100 by NADW), metal partitioning is affected by different precipitation and oxidation processes. Molar ratios normalized to Fe in the particles highlight the onset of Fe oxides formation, the precipitation of barite and the decreasing contribution of sulfide minerals (mainly Cu–Fe sulfides and sphalerite/wurtzite) along with fluid dilution. PY 2020 PD MAR SO Deep-sea Research Part I-oceanographic Research Papers SN 0967-0637 PU Elsevier BV VL 157 UT 000523712800006 DI 10.1016/j.dsr.2019.103204 ID 71060 ER EF