Preferential Riverine Export of Fine Volcanogenic Particles to the Southeast Australian Margin

Type Article
Date 2020-02
Language English
Author(s) Bayon Germain1, 2, Douglas Grant B.3, Denton Geoff J.3, Monin Laurence2, de Deckker Patrick4
Affiliation(s) 1 : IFREMER, Marine Geosciences Unit, Plouzané, France
2 : Department of Earth Sciences, Royal Museum for Central Africa, Tervuren, Belgium
3 : CSIRO Land and Water, Wembley, WA, Australia
4 : Research School of Earth Sciences, The Australian National University, Canberra, ACT, Australia
Source Frontiers In Marine Science (2296-7745) (Frontiers Media SA), 2020-02 , Vol. 7 , N. 89 , P. 15p.
DOI 10.3389/fmars.2020.00089
WOS© Times Cited 5
Keyword(s) rare earth elements, neodymium isotopes, suspended particulates, colloids, Murray-Darling Basin, Australia
Abstract

We report on rare earth element and neodymium isotopic compositions in a series of grain-size fractions separated from river suspended matter in the Murray-Darling Basin (MDB) and a nearby marine sediment core (MD03-2607) offshore south-eastern Australia. This source-to-sink approach was used to further investigate the extent to which sediment sorting may control the geochemistry of suspended loads in rivers, and to provide constraints on the source of the detrital sediment material exported to the ocean. Our results provide further compelling evidence that significant size-dependent geochemical decoupling can occur in river systems, accounting here for Nd isotopic (εNd) differences of up to eight epsilon-units between silt (>25 μm) and colloidal (0.2−0.006 μm; 0.006−0.003 μm) fractions. All suspended particulate samples from the River Murray watershed display a trend toward more radiogenic (higher εNd) Nd signatures with decreasing grain-size, in addition to differing REE signatures, which collectively point toward a preferential volcanogenic origin for the fine-grained inorganic particles transported by MDB rivers. Furthermore, we show that the same river-borne volcanogenic material dominates in the fine-grained detrital fractions extracted from core MD03-2607 at the south-eastern Australian margin; a finding corroborated by REE signatures in a series of copepod fecal pellet separates from the same core. Collectively, our results suggest that river sediment discharge is accompanied by preferential export of fine-grained volcanogenic particles to the ocean. This potential source of bioavailable trace metals and nutrients in ocean surface waters could impact marine productivity.

 

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