FN Archimer Export Format PT J TI Constraints on Earth System Functioning at the Paleocene‐Eocene Thermal Maximum From the Marine Silicon Cycle BT AF Fontorbe, Guillaume Frings, Patrick J. De La Rocha, Christina L. Hendry, Katharine R. Conley, Daniel J. AS 1:1,2;2:3,4;3:;4:5;5:1; FF 1:;2:;3:;4:;5:; C1 Department of Geology Lund University Lund, Sweden GEOMAR Helmholtz Centre for Ocean Research Kiel Kiel ,Germany Section 3.3 Earth Surface Geochemistry GFZ German Research Centre for Geosciences Potsdam, Germany Department of GeosciencesSwedish Museum of Natural History Stockholm ,Sweden School of Earth Sciences University of Bristol Bristol , UK C2 UNIV LUND, SWEDEN IFM GEOMAR, GERMANY GFZ, GERMANY NHM, SWEDEN UNIV BRISTOL, UK IF 3.277 TC 9 UR https://archimer.ifremer.fr/doc/00627/73939/73287.pdf https://archimer.ifremer.fr/doc/00627/73939/73288.pdf LA English DT Article DE ;Paleocene-Eocene Thermal Maximum;silicon biogeochemical cycle;silicon isotopes;weathering AB The Paleocene‐Eocene Thermal Maximum (PETM, ca. 56 Ma) is marked by a negative carbon isotope excursion (CIE) and increased global temperatures. The CIE is thought to result from the release of 13C‐depleted carbon, although the source(s) of carbon and triggers for its release, its rate of release, and the mechanisms by which the Earth system recovered are all debated. Many of the proposed mechanisms for the onset and recovery phases of the PETM make testable predictions about the marine silica cycle, making silicon isotope records a promising tool to address open questions about the PETM. We analyzed silicon isotope ratios (δ30Si) in radiolarian tests and sponge spicules from the Western North Atlantic (ODP Site 1051) across the PETM. Radiolarian δ30Si decreases by 0.6‰ from a background of 1‰ coeval with the CIE, while sponge δ30Si remains consistent at 0.2‰. Using a box model to test the Si cycle response to various scenarios, we find the data are best explained by a weak silicate weathering feedback, implying the recovery was mostly driven by nondiatom organic carbon burial, the other major long‐term carbon sink. We find no resolvable evidence for a volcanic trigger for carbon release, or for a change in regional oceanography. Better understanding of radiolarian Si isotope fractionation and more Si isotope records spanning the PETM are needed to confirm the global validity of these conclusions, but they highlight how the coupling between the silica and carbon cycles can be exploited to yield insight into the functioning of the Earth system. PY 2020 PD MAY SO Paleoceanography And Paleoclimatology SN 2572-4517 PU American Geophysical Union (AGU) VL 35 IS 5 UT 000537787100002 DI 10.1029/2020PA003873 ID 73939 ER EF