FN Archimer Export Format PT J TI Contribution of Sea-State Dependent Bubbles to Air-Sea Carbon Dioxide Fluxes BT AF REICHIL, B. G. DEIKE, L. AS 1:1,2;2:3,4; FF 1:;2:; C1 Princeton Univ, Program Atmospner & Ocean Sci, Princeton, NJ 08544 USA. NOAA, Geophys Fluid Dynam Lab, Princeton, NJ 08540 USA. Princeton Univ, Dept Mech & Aerosp Engn, Princeton, NJ 08544 USA. Princeton Univ, Princeton Environm Inst, Princeton, NJ 08544 USA. C2 UNIV PRINCETON, USA NOAA, USA UNIV PRINCETON, USA UNIV PRINCETON, USA IF 4.72 TC 25 UR https://archimer.ifremer.fr/doc/00676/78838/81092.pdf LA English DT Article CR OISO - OCÉAN INDIEN SERVICE D'OBSERVATION AB Breaking surface ocean waves produce bubbles that are important for air-sea gas exchanges, particularly during high winds. In this study we estimate air-sea CO2 fluxes globally using a new approach that considers the surface wave contribution to gas fluxes. We estimate that 40% of the net air-sea CO2 flux is via bubbles, with annual, seasonal, and regional variability. When compared to traditional gas-flux parameterization methods that consider the wind speed alone, we find high-frequency (daily to weekly) differences in the predicted gas flux using the sea-state dependent method at spatial scales related to atmospheric weather (10 to 100 km). Seasonal net differences in the air-sea CO2 flux due to the sea-state dependence can exceed 20%, with the largest values associated with North Atlantic and North Pacific winter storms. These results confirm that bubbles are important for global gas-flux dynamics and that sea-state dependent parameterizations may improve performance of global coupled models. PY 2020 PD MAY SO Geophysical Research Letters SN 0094-8276 PU Amer Geophysical Union VL 47 IS 9 UT 000536639500015 DI 10.1029/2020GL087267 ID 78838 ER EF