FN Archimer Export Format PT J TI Identification and quantification of plastic additives using Pyrolysis-GC/MS: a review BT AF Akoueson, Fleurine Chbib, Chaza Monchy, Sébastien Paul-Pont, Ika Doyen, Périne Dehaut, Alexandre Duflos, Guillaume AS 1:1,2;2:3;3:3;4:4;5:2;6:1;7:1; FF 1:;2:;3:;4:;5:;6:;7:; C1 ANSES – Laboratoire de Sécurité des Aliments, Boulevard du Bassin Napoléon, F-62200 Boulogne-sur-Mer, France Univ. Littoral Côte d’Opale, UMR 1158 BioEcoAgro, EA 7394, Institut Charles Viollette, USC ANSES, INRAe, Univ. Lille, Univ. Artois, Univ. Picardie Jules Verne, Uni. Liège, F-62200, Boulogne-sur-Mer, France Univ. Littoral Côte d'Opale, CNRS, Univ. Lille, UMR 8187, LOG, Laboratoire d'Océanologie et de Géosciences, F-62930 Wimereux, France Univ Brest, CNRS, IRD, IFREMER, LEMAR, F-29280 Plouzané, France C2 ANSES, FRANCE UNIV LITTORAL COTE D’OPALE, FRANCE UNIV LITTORAL COTE D'OPALE, FRANCE CNRS, FRANCE UM LEMAR IN WOS Cotutelle UMR copubli-france copubli-univ-france IF 10.754 TC 56 UR https://archimer.ifremer.fr/doc/00678/78986/81380.pdf LA English DT Article DE ;Organic plastic additives (OPAs);Plastic polymers;Py-GC/MS;Multi-shot pyrolysis AB Analysis of organic plastic additives (OPAs) associated to plastic polymers is growing. The current review outlines the characteristics and the development of (multi-step) pyrolysis coupled with a gas chromatography mass spectrometer (Py-GC/MS) for the identification and semi-quantification of OPAs. Compared to traditional methods, Py-GC/MS offers advantages like suppressing extensive steps of preparation, limiting contamination due to solvents and the possibility to analyse minute particles. Its key advantage is the successive analysis of OPAs and the polymeric matrix of the same sample. Based on the studied articles, numerous methods have been described allowing identification and, in some case, semi-quantification of OPAs. There is nevertheless no gold standard method, especially given the huge diversity of OPAs and the risks of interferences with polymers or other additives, but, among other parameters, a consensus temperature seems to arise from studies. More broadly, this review also explores many aspects on the sample preparation like weight and size of particles and calibration strategies. After studying the various works, some development prospects emerge and it appears that methodological developments should focus on better characterizing the limits of the methods in order to consider which OPAs can be quantified and in which polymers this is feasible. PY 2021 PD JUL SO Science Of The Total Environment SN 0048-9697 PU Elsevier BV VL 773 UT 000635207100039 DI 10.1016/j.scitotenv.2021.145073 ID 78986 ER EF