FN Archimer Export Format PT J TI Chemical characterization of the Punta de Fuencaliente CO2-enriched system (La Palma, NE Atlantic Ocean): a new natural laboratory for ocean acidification studies BT AF GONZALEZ-DELGADO, Sara GONZALEZ-SANTANA, David SANTANA-CASIANO, Magdalena GONZALEZ-DAVILA, Melchor HERNANDEZ, Celso A. SANGIL, Carlos CARLOS HERNANDEZ, Jose AS 1:1;2:2,3;3:2;4:2;5:1;6:1;7:1; FF 1:;2:;3:;4:;5:;6:;7:; C1 Univ La Laguna, Fac Ciencias, Dept Biologfa Anim Edafol & Geol, Canary Isl, Spain. Univ Las Palmas Gran Canaria, IOCAG ULPGC, Inst Oceanog & Cambio Global, Canary Isl, Spain. Univ Brest, LEMAR, CNRS, IRD,Ifremer, F-29280 Plouzane, France. C2 UNIV LA LAGUNA, SPAIN UNIV LAS PALMAS GRAN CANARIA, SPAIN UBO, FRANCE UM LEMAR IN WOS Cotutelle UMR DOAJ copubli-europe IF 5.092 TC 5 UR https://archimer.ifremer.fr/doc/00684/79576/82245.pdf https://archimer.ifremer.fr/doc/00684/79576/82246.zip https://archimer.ifremer.fr/doc/00684/79576/82247.pdf https://archimer.ifremer.fr/doc/00684/79576/82248.zip LA English DT Article AB We present a new natural carbon dioxide (CO2) system located off the southern coast of the island of La Palma (Canary Islands, Spain). Like CO2 seeps, these CO2 submarine groundwater discharges (SGDs) can be used as an analogue to study the effects of ocean acidification (OA) on the marine realm. With this aim, we present the chemical characterization of the area, describing the carbon system dynamics, by measuring pH, AT and CT and calculating Ω aragonite and calcite. Our explorations of the area have found several emission points with similar chemical features. Here, the CT varies from 2120.10 to 10 784.84 µmol kg−1, AT from 2415.20 to 10 817.12 µmol kg−1, pH from 7.12 to 8.07, Ω aragonite from 0.71 to 4.15 and Ω calcite from 1.09 to 6.49 units. Also, the CO2 emission flux varies between 2.8 and 28 kg CO2 d−1, becoming a significant source of carbon. These CO2 emissions, which are of volcanic origin, acidify the brackish groundwater that is discharged to the coast and alter the local seawater chemistry. Although this kind of acidified system is not a perfect image of future oceans, this area of La Palma is an exceptional spot to perform studies aimed at understanding the effect of different levels of OA on the functioning of marine ecosystems. These studies can then be used to comprehend how life has persisted through past eras, with higher atmospheric CO2, or to predict the consequences of present fossil fuel usage on the marine ecosystem of the future oceans. PY 2021 PD MAR SO Biogeosciences SN 1726-4170 PU Copernicus GmbH VL 18 IS 5 UT 000627598800002 BP 1673 EP 1687 DI 10.5194/bg-18-1673-2021 ID 79576 ER EF