FN Archimer Export Format PT J TI Silicon Isotope Analyses of Soil and Plant Reference Materials: An Inter‐Comparison of Seven Laboratories BT AF Delvigne, Camille Guihou, Abel Schuessler, Jan A. Savage, Paul Poitrasson, Franck Fischer, Sebastian Hatton, Jade E. Hendry, Katharine R. Bayon, Germain Ponzevera, Emmanuel Georg, Bastian Akerman, Alisson Pokrovsky, Oleg S. Meunier, Jean-Dominique Deschamps, Pierre Basile‐Doelsch, Isabelle AS 1:1,2;2:1;3:3,4;4:5;5:6;6:5;7:7;8:7;9:8;10:8;11:9,10;12:6;13:6,11;14:1;15:1;16:1; FF 1:;2:;3:;4:;5:;6:;7:;8:;9:PDG-REM-GM-LGS;10:PDG-REM-GM-LGS;11:;12:;13:;14:;15:;16:; C1 Aix Marseille Univ ,CNRS IRD, INRAE, Coll. France, CEREGE, Europôle Méditerranée de l’Arbois BP 80 13545 Aix‐en‐Provence cedex ,France Earth and Life Institute Environmental sciences, Université Catholique de Louvain L7.05.10 1348 Louvain‐la‐Neuve, Belgium Thermo Fisher Scientific ,Bremen ,Germany GFZ,German Research Centre for Geosciences Potsdam 14473 ,Germany School of Earth & Environmental Sciences University of St Andrews Irvine Building, St Andrews, KY16 9AL, UK Géoscience and Environment Toulouse (GET), UMR 5563 CNRS‐University of Toulouse III‐IRD‐CNES 14 Avenue Edouard Belin 31400 Toulouse ,France School of Earth Sciences ,University of Bristol Wills Memorial Building, Queens Road Bristol, UK IFREMER, Marine Geosciences Unit Brest,France Water Quality Center Trent University ,Peterborough ON K9L 1Z8 ,Canada Agilent Technologies Canada, 6705 Millcreek Dr Mississauga ON L5N 5M4 ,Canada BIO‐GEO‐CLIM ,Laboratory Tomsk State University Lenina av., 36 Tomsk, Russia C2 UNIV AIX MARSEILLE, FRANCE UNIV CATHOLIC LOUVAIN, BELGIUM THERMO FISHER SCIENTIFIC, GERMANY GFZ, GERMANY UNIV ST ANDREWS, UK UNIV TOULOUSE, FRANCE UNIV BRISTOL, UK IFREMER, FRANCE UNIV TRENT, CANADA AGILENT TECHNOL CANADA, CANADA UNIV TOMSK STATE, RUSSIA SI BREST SE PDG-REM-GM-LGS IN WOS Ifremer UPR copubli-france copubli-europe copubli-univ-france copubli-int-hors-europe IF 4.343 TC 4 UR https://archimer.ifremer.fr/doc/00684/79594/82284.pdf LA English DT Article DE ;silicon isotopes;reference materials;soil;plant;inter‐comparison of measurements AB The use of silicon (Si) isotopes has led to major advances in our understanding of Si cycling in modern and past environments. This inter‐laboratory comparison exercise provides the community with the first set of soil and plant reference materials with an analytically challenging matrix containing organic material that is known to induce isotopic bias, for use as secondary reference materials in Si isotope measurement. Seven laboratories analysed four soil reference materials (GBW‐07401, GBW‐07404, GBW‐07407, TILL‐1) and one plant reference material (ERM‐CD281). Participating laboratories employed a range of chemical preparation methods and analytical setups but all analyses were performed by MC‐ICP‐MS. Irrespective of the chemical preparation method or analytical conditions, the results show excellent agreement among laboratories within 2s for at least three replicates. Data were combined together to calculate δ29Si and δ30Si mean values (relative to NBS 28) and their expanded uncertainties (U, coverage factor k = 2). The δ30Si values are as follow: GBW‐07401: ‐0.27 ± 0.06 ‰, GBW‐07404: ‐0.76 ± 0.12 ‰, GBW‐07407: ‐1.82 ± 0.17 ‰, TILL‐1: ‐0.16 ± 0.06 ‰ and ERM‐CD281: ‐0.28 ± 0.11 ‰. Also, a compilation of published data provides an up‐to‐date mean δ30Si for BHVO‐2 of ‐0.28 ± 0.08 ‰. PY 2021 PD SEP SO Geostandards And Geoanalytical Research SN 1639-4488 PU Wiley VL 45 IS 3 UT 000644331900001 BP 525 EP 538 DI 10.1111/ggr.12378 ID 79594 ER EF