FN Archimer Export Format PT J TI The Segmented Zambezi Sedimentary System from Source to Sink: 2. Geochemistry, Clay Minerals, and Detrital Geochronology BT AF Garzanti, Eduardo Bayon, Germain Dinis, Pedro Vermeesch, Pieter Pastore, Guido Resentini, Alberto Barbarano, Marta Ncube, Lindani Van Niekerk, Helena Johanna AS 1:1;2:2;3:3;4:4;5:1;6:1;7:1;8:5;9:5; FF 1:;2:PDG-REM-GEOOCEAN-ASTRE;3:;4:;5:;6:;7:;8:;9:; C1 Laboratory for Provenance Studies, Department of Earth and Environmental Sciences, University of Milano-Bicocca, 20126 Milano, Italy Unité de Recherche Geosciences Marines, Ifremer, CS 10070, 29280 Plouzané, France MARE-Marine and Environmental Sciences Centre, Department of Earth Sciences, University of Coimbra, Portugal London Geochronology Centre, Department of Earth Sciences, University College London, London, WC1E 6BT, UK Department of Environmental Sciences, University of South Africa, Pretoria, South Africa C2 UNIV MILANO, ITALY IFREMER, FRANCE UNIV COIMBRA, PORTUGAL UNIV COLL LONDON, UK UNIV SOUTH AFRICA, SOUTH AFRICA SI BREST SE PDG-REM-GEOOCEAN-ASTRE UM GEO-OCEAN IN WOS Ifremer UMR copubli-europe copubli-int-hors-europe copubli-sud IF 1.8 TC 8 UR https://archimer.ifremer.fr/doc/00750/86185/91450.pdf LA English DT Article AB Elemental geochemistry, Nd isotopes, clay minerals, and U-Pb zircon ages integrated by petrographic and heavy-mineral data offer a multi-proxy panorama of mud and sand composition across the Zambezi sediment-routing system. Detrital-zircon geochronology highlights the four major episodes of crustal growth in southern Africa: Irumide ages predominate over Pan-African, Eburnean, and Neoarchean ages. Smectite, dominant in mud generated from Karoo basalts or in the equatorial/winter-dry climate of Mozambican lowlands, prevails over illite and kaolinite. Elemental geochemistry reflects quartz addition by recycling (Uppermost Zambezi), supply from Karoo basalts (Upper Zambezi), and first-cycle provenance from Precambrian basements (Lower Zambezi). Mildly negative for sediments derived from mafic granulites, gabbros, and basalts, åNd values are most negative for sand derived from cratonic gneisses. Intrasample variability among cohesive mud, very coarse silt, and sand is principally caused by the concentration of Nd-rich monazite in the fine tail of the size distribution. The settling-equivalence effect also explains deviations from the theoretical relationship between åNd and TNd,DM model ages, suggesting that monazite carries a more negative åNd signal than less dense and less durable heavy minerals. Elemental geochemistry and Nd isotopes reveal that the Mazowe-Luenha river system contributes most of the sediment reaching the Zambezi Delta today, with minor supply by the Shire River. Sediment yields and erosion rates are lower by an order of magnitude on the low-relief Kalahari Plateau than in rugged Precambrian terranes. On the Plateau, mineralogical and geochemical indices testify to extensive breakdown of feldspars and garnet unjustified by the presently dry climate. Detrital kaolinite is recycled by incision of Cretaceous- Cenozoic paleosols even in the wetter lower catchment, where inefficient hydrolysis is testified by abundant fresh feldspars and undepleted Ca and Na. Mud geochemistry and surficial corrosion of ferromagnesian minerals indicate that, at present, weathering increases only slightly downstream the Zambezi River. PY 2022 PD MAY SO Journal Of Geology SN 0022-1376 PU University of Chicago Press VL 130 IS 3 UT 000793503600001 BP 171 EP 208 DI 10.1086/719166 ID 86185 ER EF