FN Archimer Export Format PT J TI Nickel and chromium stable isotopic composition of ureilites: implications for the Earth’s core formation and differentiation of the ureilite parent body BT AF Zhu (朱柯), Ke Barrat, Jean-Alix Yamaguchi, Akira Rouxel, Olivier Germain, Yoan Langlade, Jessica Moynier, Frederic AS 1:1,2;2:3,4;3:5;4:6;5:6;6:4;7:2; FF 1:;2:;3:;4:PDG-REM-GEOOCEAN;5:PDG-REM-GEOOCEAN-CYBER;6:;7:; C1 Freie Universität Berlin Institut für Geologische Wissenschaften Malteserstr. 74‐10012249 Berlin ,Germany Université de Paris Institut de Physique du Globe de Paris CNRS UMR 7154 1 rue Jussieu Paris75005 ,France Institut Universitaire de France, France Univ Brest, CNRS, IRD, Ifremer, LEMAR F‐29280 Plouzané, France National Institute of Polar Research 10‐3 Midori‐choTachikawa Tokyo190‐8518, Japan Unité de Géosciences Marines IFREMER, Z.I. Pointe du diable BP 70‐29280 Plouzané ,France C2 UNIV FREE BERLIN, GERMANY UNIV PARIS, FRANCE INST UNIV FRANCE, FRANCE CNRS, FRANCE NIPR, JAPAN IFREMER, FRANCE SI BREST SE PDG-REM-GEOOCEAN PDG-REM-GEOOCEAN-CYBER UM LEMAR GEO-OCEAN IN WOS Ifremer UMR WOS Cotutelle UMR copubli-france copubli-europe copubli-univ-france copubli-int-hors-europe IF 5.2 TC 10 UR https://archimer.ifremer.fr/doc/00756/86794/92269.pdf https://archimer.ifremer.fr/doc/00756/86794/92270.pdf LA English DT Article DE ;ureilites;Ni stable isotopes;Cr stable isotopes;core formation;partial melting;mantle heterogeneity AB We report the first Ni and Cr stable isotope data for ureilite meteorites that are the mantle residue of a carbon-rich differentiated planet. Ureilites have similar Ni stable isotope compositions as chondrites, suggesting the core-mantle differentiation of ureilite parent body did not fractionate Ni isotopes. Since the size of Earth is potentially larger than that of ureilite parent body (UPB; with diameter > 690 km), resulting in higher temperatures at the core-mantle boundary of Earth, it can be predicted that the terrestrial core formation may not directly cause Ni stable isotope fractionation. On the other hand, we also report high-precision Cr stable isotope composition of ureilites, including one ureilitic trachyandesite (ALM-A) that is enriched in lighter Cr stable isotopes relative to the main-group ureilites, which suggests the partial melting occurred on UPB. The globally heavy Cr in the UPB compared to chondrites can be caused by sulfur-rich core formation processes. Plain Language Summary The stable isotope fractionation of siderophile elements is robust to trace the planetary core formation processes. However, whether nickel (Ni) isotopes fractionate during the core formation is highly debated, since the origin of Ni stable isotope difference between bulk silicate Earth (BSE) and chondrites is not clear. Here, we report high-precision Ni stable isotope data (expressed as δ60/58Ni, the per mil deviation of 60Ni/58Ni ratios relative to NIST SRM 986) for ureilite meteorites that come from the mantle of a carbon-rich differentiated body. Ureilites have an average δ60/58Ni value of 0.26 ± 0.13‰ (2SD, N = 22) that is highly consistent with that of chondrites with δ60/58Ni = 0.23 ± 0.14‰ (2SD, N = 37), which suggests planetary core formation does not effectively fractionate Ni stable isotopes. There is a ureilite trachyandesite that enriches lighter Cr stable isotopes (δ53Cr = -0.11 ± 0.02‰; δ53Cr as the per-mil deviation of 53Cr/52Cr ratios relative to NIST SRM 979) relative to the main-group ureilites (δ53Cr = -0.05 ± 0.04‰; 2SD, N = 10), which suggests the partial melting occurred on ureilite parent body (UPB). The globally heavy Cr in the UPB compared to chondrites can be caused by sulfur-rich core formation processes. PY 2022 PD APR SO Geophysical Research Letters SN 0094-8276 PU American Geophysical Union (AGU) VL 49 IS 7 UT 000778516500001 DI 10.1029/2021GL095557 ID 86794 ER EF