FN Archimer Export Format PT J TI Mixed carbonate-siliceous hydrothermal chimneys ahead of the Asal propagating rift (SE Afar Rift, Republic of Djibouti) BT AF Moussa, Nima Bayon, Germain Dekov, V. Yamanaka, T. Shinjo, R. Toki, T. Le Gall, Bernard Grassineau, N. Langlade, Jessica Awaleh, M.O. Pelleter, Ewan AS 1:1;2:2;3:3;4:3;5:4,5;6:5,6;7:7;8:8;9:9;10:1;11:2; FF 1:;2:PDG-REM-GEOOCEAN-ASTRE;3:;4:;5:;6:;7:;8:;9:;10:;11:PDG-REM-GEOOCEAN-CYBER; C1 Institut des Sciences de la Terre, Centre d’Etudes et de Recherches de Djibouti, B.P. 486, Djibouti Univ Brest, CNRS, Ifremer, Geo-Ocean, F-29280, Plouzané, France Department of Ocean Sciences, Tokyo University of Marine Science and Technology, 4-5-7 Konan, Minato-ku, Tokyo, 108-8477, Japan Department of Physics and Earth Sciences, Faculty of Science, University of the Ryukyus, 1 Senbaru, Nishihara, Okinawa, 903-0213, Japan Research Institute for Humanity and Nature, 457-4 Motoyama, Kamigamo, Kita-ku, Kyoto, 603-8047, Japan Department of Chemistry, Biology and Marine Science, Faculty of Science, University of the Ryukyus, 1 Senbaru, Nishihara, Okinawa, 903-0213, Japan UMR/CNRS 6538 Géosciences Océan, UBO-IUEM, Place Nicolas Copernic, 29280, Plouzané, France Department of Earth Sciences, Royal Holloway University of London, EGHAM Surrey, TW20 0EX, UK CNRS, IUEM, UMS 3113, F-29280, Plouzané, France C2 CERD, DJIBOUTI IFREMER, FRANCE UNIV TOKYO, JAPAN UNIV RYUKYUS, JAPAN RIHN, JAPAN UNIV RYUKYUS, JAPAN UBO, FRANCE UNIV LONDON, UK CNRS, FRANCE SI BREST SE PDG-REM-GEOOCEAN-ASTRE PDG-REM-GEOOCEAN-CYBER UM GEO-OCEAN IN WOS Ifremer UMR WOS Cotutelle UMR copubli-france copubli-europe copubli-univ-france copubli-int-hors-europe copubli-sud IF 2.3 TC 1 UR https://archimer.ifremer.fr/doc/00799/91132/96809.pdf LA English DT Article DE ;SE Afar Rift;Hydrothermal chimneys;Isotopic analyses;Allols sites;Djibouti AB Numerous active and fossil hydrothermal carbonate chimneys have been reported at Lake Asal and Lake Abhe, in the southeastern part of the Afar Rift (Republic of Djibouti): a tectonically and volcanically active region for the last 30 million years. In this study, we report on a detailed mineralogical and geochemical investigation of unusual hydrothermal mixed carbonate-siliceous chimneys recently discovered in the Allols area (Harralol, Haralé Awda and Sakallol), northwest of the Asal Rift. These inactive chimneys, up to 20 m high, consist of tall spires partly stained by Fe-oxides. They are located along major faults and were formed sub-aqueously when the area was occupied by a lake. Hydrothermal carbonate structures were also found in the same area. The oxygen (δ18O) and carbon (δ13C) isotopic compositions of the chimneys range from −4.5 to 25.3‰ and from −9.44 to 8.92‰, respectively, indicating mixing between magmatic and surficial waters. Their radiogenic Sr isotopic compositions (87Sr/86Sr = 0.7049–0.7056) show values typical of altered basaltic rocks. Chimneys also exhibit negative Ce anomaly suggestive of a genetic link with basalt alteration. Overall, this study suggests that lake water chemistry in the Allols area experienced major changes in the past, reflecting various contributions of mixing fluids (lake water and hydrothermal fluids), leading alternatively to deposition of carbonate chimneys and precipitation of (and/or replacement with) silica. PY 2023 PD JAN SO Journal Of African Earth Sciences SN 1464-343X PU Elsevier BV VL 197 UT 000882458000002 DI 10.1016/j.jafrearsci.2022.104765 ID 91132 ER EF