FN Archimer Export Format PT J TI Assessing and predicting the changes for inorganic mercury and methylmercury concentrations in surface waters of a tidal estuary (Adour Estuary, SW France) BT AF Stoichev, Teodor Thibaut de Chanvalon, Aubin Veloso, Sandrine Deborde, Jonathan Tessier, Emmanuel Lanceleur, Laurent Amouroux, David AS 1:1;2:2;3:2;4:2,3;5:2;6:2;7:2; FF 1:;2:;3:;4:PDG-ODE-LITTORAL-LERPC;5:;6:;7:; C1 Interdisciplinary Center of Marine and Environmental Research (CIIMAR/CIMAR), University of Porto, Terminal de Cruzeiros de Leixoes, Av. General Norton de Matos s/n, 4450-208 Matosinhos, Portugal Universite de Pau et des Pays de l'Adour, E2S UPPA, CNRS, IPREM, Institut des Sciences Analytiques et de Physico-chimie pour l'Environnement et les matériaux, Pau, France Ifremer, LITTORAL, Laboratoire Environnement Ressources des Pertuis Charentais, F-17390 La Tremblade, France C2 CIIMAR/CIMAR, PORTUGAL UNIV PAU & PAYS ADOUR, FRANCE IFREMER, FRANCE SI LA TREMBLADE SE PDG-ODE-LITTORAL-LERPC IN WOS Ifremer UPR copubli-france copubli-europe copubli-univ-france IF 5.8 TC 5 UR https://archimer.ifremer.fr/doc/00808/91960/99583.pdf LA English DT Article DE ;Effect separation;Contaminant transport;Pollution sources;Analysis of covariance;Mercury speciation;Water AB Total and dissolved concentrations of inorganic mercury (IHg) and methylmercury (MeHg) in water (Adour Estuary) were determined during three sampling campaigns and related to biogeochemical variables (nutrients, organic matter). Factors (sampling time, sample type) were included in analysis of covariance with effect separation. The urban estuary suffered historically from anthropogenic sources, however, decreased emissions have reduced Hg concentrations. Total IHg (0.51–3.42 ng L−1) and MeHg (25–81 pg L−1) concentrations are additively described by suspended particulate matter and particulate organic carbon. Higher total concentrations, carried by organic-rich particles, were found near specific discharge points (0.79–8.02 ng L−1 and 34–235 pg L−1 for IHg and MeHg, respectively). The associated high dissolved MeHg concentrations could not be explained only by biogeochemical variables. Better efficiency of the models is found for total than for dissolved concentrations. Models should be checked with other contaminants or with estuaries, suffering from downstream contamination. PY 2023 PD JAN SO Marine Pollution Bulletin SN 0025-326X PU Elsevier BV VL 186 UT 000908054300002 DI 10.1016/j.marpolbul.2022.114400 ID 91960 ER EF