FN Archimer Export Format PT J TI Volatiles of the active Mayotte volcanic chain: STA & EGA-MS analysis of volcanic products BT AF Thivet, Simon Hess, Kai-Uwe Dingwell, Donald B. Berthod, Carole Gurioli, Lucia Di Muro, Andrea Lacombe, Tristan Komorowski, Jean-Christophe AS 1:1;2:1;3:1;4:2,3;5:4;6:5;7:4;8:2; FF 1:;2:;3:;4:;5:;6:;7:;8:; C1 Ludwig-Maximilians-Universität, Department of Earth and Environmental Sciences, 80333 Munich, Germany Université Paris Cité, Institut de Physique du Globe de Paris, CNRS, 75005 Paris, France Observatoire Volcanologique et Sismologique de la Guadeloupe, Institut de physique du globe de Paris, 97113 Gourbeyre, France Laboratoire Magmas et Volcans, Université Clermont Auvergne, CNRS, IRD, OPGC, 63178 Aubière, France Laboratoire de Géologie de Lyon : Terre, Planètes, Environnement, UMR 5276, CNRS, Ecole Normale Supérieure de Lyon, Université Claude Bernard Lyon 1, 69622 Villeurbanne, France C2 UNIV MUNICH, GERMANY UNIV PARIS CITE, FRANCE OBSERV VOLCANOLOG GUADELOUPE, FRANCE UNIV CLERMONT AUVERGNE, FRANCE UNIV LYON, FRANCE IF 3.9 TC 2 UR https://archimer.ifremer.fr/doc/00813/92540/99151.pdf LA English DT Article CR MAYOBS MAYOBS1 MAYOBS17 MAYOBS2 MAYOBS4 MD 228 / MAYOBS15 BO Marion Dufresne Pourquoi pas ? DE ;Basanite;Evolved gas analysis by mass spectrometry;Magma;Phonolite;Simultaneous thermal analysis AB In July 2018, a large (ca. 6.55 km3), deep (ca. 2.5 to 3.3 km b.s.l) submarine eruption started ca. 50 km east of Mayotte Island. Samples of fresh basanitic lava rims were collected by dredging, at various times and locations from the newly formed Fani Maoré Edifice (FME). The logistical response to this extraordinary event also enabled the dredging of shallow (ca. 1.2 to 1.6 km below sea level, b.s.l.), fresh phonolitic lava and bomb rims in the so-called Horse-Shoe Area (HSA), ca. 15 km east of Mayotte. Better-known subaerial counterparts of Holocene age, have also been sampled in the La Vigie Maar (LVM) phonolitic deposits (Petite-Terre, Mayotte Island), for comparison with submarine samples. These samples belong to a single volcanic chain that extends from LVM to FME passing through HSA. A novel combination of Simultaneous Thermal Analysis (STA), which involves Differential Scanning Calorimetry (DSC), Thermal Gravimetry Analysis (TGA), and Evolved Gas Analysis conducted by Mass Spectrometry (EGA-MS), enable a reconstruction of the volatile distributions and compositions (H2O, CO2, and SO2) of these samples. Calorimetric and degassing profiles of controlled heating runs reveal different volatile reservoirs distributed as a function of sample textures and compositions, which have been further investigated by Scanning Electron Microscopy (SEM), Electron Probe Micro-Analysis (EPMA), and Raman spectroscopy. A linear correlation observed between the TGA and H2O-EGA-MS signal intensities also enables the quantification of adsorbed-external vs. dissolved-magmatic H2O contents of the studied samples. The novel application of this approach to volcanic products is thus confirmed as a reliable method to determine volatile characteristics in a wide range of samples, yielding a quantitative description of volatile behavior within the associated magmatic systems and eruptions. PY 2023 PD FEB SO Chemical Geology SN 0009-2541 PU Elsevier BV VL 618 UT 000954339800001 DI 10.1016/j.chemgeo.2022.121297 ID 92540 ER EF