FN Archimer Export Format PT J TI Two types of slab components under Ecuadorian volcanoes supported by primitive olivine-hosted melt inclusion study BT AF Narváez, D.F. Samaniego, P. Koga, K.T. Rose-Koga, E.F. Hidalgo, S. Ratzov, Gueorgui AS 1:1,2;2:1;3:1;4:1;5:3;6:4; FF 1:;2:;3:;4:;5:;6:; C1 Université Clermont Auvergne, CNRS, IRD, OPGC, Laboratoire Magmas et Volcans, F-63000 Clermont-Ferrand, France Departamento de Geología, Facultad de Ingeniería en Geología y Petróleos, Escuela Politécnica Nacional, Quito, Ecuador Instituto Geofísico, Escuela Politécnica Nacional, Ladrón de Guevara E11-253, Aptdo 2759, Quito, Ecuador Université Côte d'Azur, CNRS, IRD, Observatoire de la Côte d'Azur, Géoazur, 250 rue Albert Einstein, Sophia Antipolis, 06560 Valbonne, France C2 UNIV CLERMONT AUVERGNE, FRANCE ESCUELA POLITEC NACL, ECUADOR INST GEOFISICO, ECUADOR UNIV NICE, FRANCE IF 3.5 TC 0 UR https://archimer.ifremer.fr/doc/00819/93061/99582.pdf LA English DT Article CR AMADEUS BO L'Atalante DE ;Primitive magma;Subduction zone;Trace element;Mantle metasomatism;Northern Volcanic Zone;Andes AB The origin of several geochemical parameters in continental arc lavas (e.g., La/Yb, Ba/Th) is controversial as to whether it is imparted by the slab or acquired in the crust. In Ecuador, where volcanoes are built over a thick crust (~50 km), this problem is grounded in the lack of primitive rocks. Here, we use melt inclusions hosted in Fo80–90 olivines to decipher the slab component signatures that metasomatises the sub-arc mantle. We report major, trace, and volatile elements analyzed in experimentally heated melt inclusions, which are from primitive rocks of Cotacachi, Cubilche, Cono de la Virgen, Conos de Licto, and Sangay volcanoes located in the north and south of the Ecuadorian arc. Based on trace element data and geochemical modeling, we recognize two types of slab components: one is indicative of aqueous fluids (e.g., high Ba/La, Pb/Ce, B/Nb), and the other is indicative of hydrous siliceous melts (e.g., high La/Nb, Th/Nb). The aqueous fluid signature is recognized in all volcanoes (except for Cono de la Virgen), and their F/Cl are distributed around 0.43 ± 0.07, independent of the distance to the Benioff zone. We propose a model where hydrous siliceous melts result from the subduction of a young oceanic crust north of the Grijalva fracture zone. Additionally, we show that the mantle under Licto and Sangay volcanoes is enriched prior to metasomatism by slab fluids. This study shows that melt inclusions give valuable insights into the composition of primitive melts that are rarely accessible as whole rocks. PY 2023 PD APR SO Lithos SN 0024-4937 PU Elsevier BV VL 442-443 UT 000995016900001 DI 10.1016/j.lithos.2023.107049 ID 93061 ER EF