FN Archimer Export Format PT J TI On the combination of the planktonic foraminiferal Mg/Ca, clumped (Δ47) and conventional (δ18O) stable isotope paleothermometers in palaeoceanographic studies BT AF Peral, Marion Bassinot, Franck Daëron, Mathieu Blamart, Dominique Bonnin, Jérôme Jorissen, Frans Kissel, Catherine Michel, Elisabeth Waelbroeck, Claire Rebaubier, Helene Gray, William R AS 1:1;2:1;3:1;4:1;5:2;6:3;7:1;8:1;9:4;10:1;11:1; FF 1:;2:;3:;4:;5:;6:;7:;8:;9:;10:;11:; C1 Laboratoire des Sciences du Climat et de l’Environnement, LSCE/IPSL, CEA-CNRS-UVSQ, Université Paris-Saclay, France Université de Bordeaux, CNRS, Environnements et Paléoenvironnements Océaniques et Continentaux (EPOC), UMR 5805, Allée Geoffroy St Hilaire, 33615 Pessac Cedex, France UMR CNRS 6112 LPG-BIAF Bio-Indicateurs Actuels et Fossiles, Université d’Angers, 2, Boulevard Lavoisier, 49045 Angers Cedex, Franc LOCEAN/IPSL, Sorbonne Université-CNRS-IRD-MNHN, UMR7159, Paris, France C2 UNIV PARIS SACLAY, FRANCE UNIV BORDEAUX, FRANCE UNIV ANGERS, FRANC UNIV SORBONNE, FRANCE IF 5 TC 4 UR https://archimer.ifremer.fr/doc/00821/93251/99878.pdf LA English DT Article CR IMAGES 1-MD101 MD 119 / TIP 2000 MD 127 / PAGE MD 132 / P.I.C.A.S.S.O.-IMAGES11 MD 136 / VIGO MD 168 / AMOCINT (IMAGES XVII) MD 189 / INDIEN SUD 2 MD 190 / CIRCEA BO Marion Dufresne AB Assuming that foraminiferal clumped isotope (Δ47) values are independent of seawater salinity and pH, the combination of Mg/Ca, δ18O and Δ47 values, may in theory allow us to disentangle the temperature, salinity/δ18Osw and pH signals. Here, we present a new Mg/Ca-Δ47 dataset for modern planktonic foraminifera, from various oceanographic basins and covering a large range of temperatures (from 0.2 to 25.4 °C). These measurements were performed on the same samples and species as the ones used for the foraminiferal Δ47 calibration of Peral et al. (2018), allowing comparison between both Mg/Ca and Δ47 paleothermometers (excluding the two benthic foraminiferal data points). There is a good agreement between these two paleothermometers when the Mg/Ca-temperature is corrected for seawater salinity and pH, suggesting that foraminiferal Δ47 may not be influenced by salinity or pH. However, our results show that Δ47 temperature uncertainties still limit our ability to reconstruct pH and δ18Osw from the combination of Mg/Ca, δ18O and Δ47 in a useful manner. We also find that disagreements between Mg/Ca and Δ47 values in G. bulloides persist after correction for vital, salinity and pH effects, suggesting that other process(es) may also influence Mg/Ca in this species. This study also provides an updated I-CDES version of the previously published planktonic and benthic foraminiferal Δ47 calibration of Peral et al. (2018), covering a range of temperature from −2 to 25.4 °C. PY 2022 PD DEC SO Geochimica Et Cosmochimica Acta SN 0016-7037 PU Elsevier BV VL 339 UT 000887436800003 BP 22 EP 34 DI 10.1016/j.gca.2022.10.030 ID 93251 ER EF