FN Archimer Export Format PT J TI Trace elements and arsenic speciation in Paracentrotus lividus from North-West Mediterranean Sea BT AF Leufroy, Axelle Bouchoucha, Marc Riviere, Gilles Guérin, Thierry Jitaru, Petru AS 1:1;2:2;3:3;4:4;5:1; FF 1:;2:PDG-ODE-LITTORAL-LERPAC;3:;4:;5:; C1 Laboratory for Food Safety, & Safety (ANSES), Université Paris Est, 94706, Maisons-Alfort, France Laboratoire Environnement Ressources Provence Azur Corse, Ifremer, CS 20330, F-83507, La Seyne Sur Mer, France Risk Assessment Department, French Agency for Food, Environmental and Occupational Health & Safety (ANSES), 94700, Maisons-Alfort, France Strategy and Programmes Department, French Agency for Food, Environmental and Occupational Health & Safety (ANSES), 94700, Maisons-Alfort, France C2 UNIV PARIS EST, FRANCE IFREMER, FRANCE ANSES, FRANCE ANSES, FRANCE SI TOULON SE PDG-ODE-LITTORAL-LERPAC TC 0 UR https://archimer.ifremer.fr/doc/00861/97256/107257.pdf LA English DT Article DE ;Trace elements;Arsenic speciation;Urchins;North-West Mediterranean Sea AB Levels of 14 trace elements (Al, Ti, V, Cr, Mn, Co, Ni, Zn, As, Se, Cd, Sn, Hg, and Pb) and 5 arsenic species (arsenite/As(III), arsenate/As(V), monomethylarsonic acid/MA, dimethylarsinic acid/DMA, and arsenobetaine/AsB) were assessed in the gonads of sea urchin samples (Paracentrotus lividus) from North-West Mediterranean Sea (French coast). The samples were collected from 13 sites characterized by different types and levels of chemical contamination. Trace elements levels were measured by inductively coupled plasma-mass spectrometry (ICP-MS) following microwave (acid) digestion in a closed system, whereas As speciation analysis was carried out by ion-exchange liquid chromatography coupled with ICP-MS after microwave-assisted extraction. High levels of trace elements were found in sea urchins sampled from Corsica whereas the samples from Théoule were found to be the least contaminated. From all the analyzed urchin samples, none showed Cd, Hg, or Pb concentrations above the regulatory levels set by the European Community (EC) No. 1881/2006 for seafood or bivalve mollusks. Regarding arsenic speciation, AsB was confirmed to be the predominant species. Inorganic As (As(III) + As(V)) was mainly constituted by As(III), which was quantified in all samples. Methylated As forms (MA and DMA) represent 9 to 23% of the total As. PY 2023 PD NOV SO Environmental Science and Pollution Research SN 1614-7499 PU Springer Science and Business Media LLC VL 30 DI 10.1007/s11356-023-30941-7 ID 97256 ER EF