The diffusion behaviour of the grain-growth inhibitors (GGI) Cr and V during early sintering stages from 950-1150 °C was investigated by means of diffusion couples of the type WC-GGI-binder/WC-binder. Besides Co, also alternative Fe/Ni and Fe/Co/Ni binder alloys were investigated. It was found that the diffusion in green bodies differs significantly from sintered hardmetals. Diffusivities in the binder phase were determined from diffusion couples prepared from model alloys and were found to be almost equal for Co and alternative binder alloys. The diffusion parameters determined from green bodies allowed to estimate the GGI distribution in a hardmetal during heat up. This was subsequently used to estimate an appropriate grain size of VC and Cr3C2 in hardmetals, which is required to ensure a sufficient GGI distribution during sintering before WC grain-growth initiates.