On the sedimentological origin of down-core variations of bulk sedimentary nitrogen isotope ratios

Type Article
Date 2005-05
Language English
Author(s) Kienast M1, 2, Higginson Mj3, Mollenhauer G2, Eglinton Ti2, Chen Mt4, Calvert Se1
Affiliation(s) 1 : Department of Earth and Ocean Sciences, University of British Columbia, Vancouver, British Columbia, Canada
2 : Department of Marine Chemistry and Geochemistry, Woods Hole Oceanographic Institution, Woods Hole, Massachusetts, USA
3 : School for Marine Science and Technology, University of Massachusetts at Dartmouth, New Bedford, Massachusetts, USA
4 : Institute of Applied Geosciences, National Taiwan Ocean University, Keelung, Taiwan
Source Paleoceanography (0883-8305) (Amer Geophysical Union), 2005-05 , Vol. 20 , N. 2 / PA2009 , P. 1-13
DOI 10.1029/2004PA001081
WOS© Times Cited 50
Abstract The bulk sedimentary nitrogen isotopic composition of two cores from nearby sites on the northern slope of the South China Sea ( Site 17940 and Ocean Drilling Program (ODP) Site 1144) differs by up to > 2 parts per thousand during the last glacial period. Given their close proximity, both core sites are located in the same biogeographic zone and nutrient regime, and it is thus unlikely that this offset is due to a true gradient in surface ocean conditions. In an attempt to resolve this offset, we have investigated the possible effects of two sedimentological parameters that can affect bulk sedimentary delta(15)N, namely, the variable contribution of inorganic N to bulk N in the sediment and the grain-size dependence of bulk delta(15)N. We find that neither effect, singly or in combination, is sufficient to explain the significant delta(15)N offset between the two down-core records. By elimination the most likely explanation for the observed discrepancy is a different origin of both the organic and inorganic nitrogen at each site. This study adds to the growing body of evidence highlighting the complex nature and origin of the sedimentary components in sediment drifts, such as ODP Site 1144.
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