Chronology and sources of trace elements accumulation in the Rhône pro-delta sediments (Northwestern Mediterranean) during the last 400years

Type Article
Date 2018-04
Language English
Author(s) Cossa Daniel1, 2, Fanget Anne-Sophie3, 7, Chiffoleau Jean-Francois2, Bassetti M-A3, Buscail R.3, Dennielou BernardORCID4, Briggs K.5, Arnaud M6, Guedron S.1, Berne Serge3
Affiliation(s) 1 : Univ Grenoble Alpes, ISTerre, BP 53, F-38041 Grenoble, France.
2 : Ifremer, LBCM, BP 21105, F-44311 Nantes, France.
3 : Univ Perpignan, CEFREM, 52 Ave P Alduy, F-66860 Perpignan, France.
4 : Ifremer, Geosci Marines, BP 70, F-29280 Plouzane, France.
5 : Univ Ottawa, Dept Phys, Ottawa, ON K1N 6N5, Canada.
6 : IRSN, BP 330, F-83507 La Seyne Sur Mer, France.
7 : Aarhus Univ, Dept Geosci, Hoegh Guldbergs Gade 2, DK-8000 Aarhus C, Denmark.
Source Progress In Oceanography (0079-6611) (Pergamon-elsevier Science Ltd), 2018-04 , Vol. 163 , P. 161-171
DOI 10.1016/j.pocean.2017.01.008
WOS© Times Cited 5
Abstract The Rhône pro-delta sediments receive the particulate inputs from the Rhône River, the largest freshwater discharge of the Western Mediterranean Sea. Trace element (TEs: Ag, Cd, Co, Cr, Cu, Ni, Pb, and Zn) concentrations and stable Pb isotope ratios were determined along a 7.7-meter-long sediment core collected from the Rhône prodeltaic lobe, archiving the deposits of the last 400 years. Trace element mean concentrations during the pre-industrialized era (before 1850 AD) were no different from the average composition of Earth’s upper crust, except for Cr. Principal component analysis, performed on TEs and tracers, suggests three origins for TEs that we identified as (i) marine biogenic material (Ag, Cd), (ii) ultramafic rocks (Li, Cr, Ni), and (iii) other clay minerals (Co, Cu, Pb and Zn). During the pre-industrial period, several changes in the TE/Al ratios coincided with flood events or/and modifications in the channelization of the Rhône River mouth. Some frequencies in the TEs temporal variations allow us to hypothesize some influence of climate variation. Sediments deposited after 1850 AD exhibited concentrations of certain TEs exceeding 1.3 to 3.5 times the concentrations of the pre-industrial era (Ag> Cd-Pb>Cu-Zn). Principal component analysis, performed on post-1850 AD data, allows to distinguish pristine and “anthropogenically impacted” TEs. Pristine TEs, such as Co, Cr, and Ni, are linked with clay markers (Al, Li and Fe), Co and Ni are associated with Mn-enrichment, whereas Cr is correlated with Fe. “Anthropogenically impacted” elements consist of Ag, Cd, Cu, Pb, and Zn. Vertical profiles show that TE contamination has increased dramatically after the IInd World War and reached a maximum between 1970 and 1980, consistently with anthropogenic atmospheric emissions changes. Sediment deposited on the Rhône prodelta at the beginning of XVIIth Century have 206/207Pb ratios close to values of natural Pb (1.200), whereas sediments deposited after 1850 AD are clearly contaminated by European gasoline and industrial Pb pools (<1.180). In addition, peak-events can be related to flooding periods, natural and man-induced channelization of the Rhône River mouth, or diagenetic processes.
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Cossa Daniel, Fanget Anne-Sophie, Chiffoleau Jean-Francois, Bassetti M-A, Buscail R., Dennielou Bernard, Briggs K., Arnaud M, Guedron S., Berne Serge (2018). Chronology and sources of trace elements accumulation in the Rhône pro-delta sediments (Northwestern Mediterranean) during the last 400years. Progress In Oceanography, 163, 161-171. Publisher's official version : https://doi.org/10.1016/j.pocean.2017.01.008 , Open Access version : https://archimer.ifremer.fr/doc/00371/48209/