Rôle des particules sur le comportement et la spéciation de métaux traces: exemple du cadmium

The role of particles in the behavior and speciation of trace metals: the cadmium example

Type Article
Date 2007-08
Language French, English
Author(s) Gonzalez Jean-Louis1, Thouvenin Benedicte1, Dange Catherine1
Affiliation(s) 1 : IFREMER, Département « Biogéochimie & Ecotoxicologie » Z. P. de Brégaillon, B.P. 330, 83507 La Seyne sur Mer, France
Source La Houille Blanche (0018-6368) (EDP Sciences), 2007-08 , N. 4 , P. 56-62
DOI 10.1051/lhb:2007047
Note Section : Qualités des eaux marines : sédiments et thermique
Keyword(s) particles, speciation, sorption/desorption, cadmium, modeling, surface properties
Abstract

The role of particles in the fate and speciation of trace metals in macrotidal estuaries was studied using a surface complexation model (MOCO). Cadmium was selected as the target metal contaminant due to its reactivity in estuaries: cadmium behavior is mainly controlled by heterogeneous processes (sorption/desorption) related to salinity and suspended matter gradients.Various scenarios of suspended matter distribution according to salinity were simulated. The impact of surface properties (specific surface area, density of surface sites, acidity instrinsic properties and complexation constant) was evaluated using data collected on particles from the Gironde, Loire and Seine estuaries.

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Gonzalez Jean-Louis, Thouvenin Benedicte, Dange Catherine (2007). Rôle des particules sur le comportement et la spéciation de métaux traces: exemple du cadmium / The role of particles in the behavior and speciation of trace metals: the cadmium example. La Houille Blanche, (4), 56-62. Publisher's official version : https://doi.org/10.1051/lhb:2007047 , Open Access version : https://archimer.ifremer.fr/doc/00480/59152/